Molecular species in liquid carboxylic acids

Michael Bobik, Friedrich Kohler, Gustav Heger, Hans Lischka, Peter Schuster

Research output: Contribution to journalArticle

8 Scopus citations

Abstract

Measurements of dielectric permittivity and electric conductance are presented for mixtures of carboxylic acids - formic, trifluoroacetic, acetic and propionic - and non-polar liquids. For the dielectric and associative behavior of carboxylic acids a knowledge of the cis-trans conformational equilibria of the monomeric acid molecules seems to be essential. Therefore the cis and trans conformations of these molecules have been calculated by the CNDO/2 and PCILO methods. Appreciable rotational barriers for their interconversion have been obtained.

Original languageEnglish
Pages (from-to)66-71
Number of pages6
JournalChemical Physics Letters
Volume40
Issue number1
DOIs
StatePublished - May 15 1976

Fingerprint Dive into the research topics of 'Molecular species in liquid carboxylic acids'. Together they form a unique fingerprint.

  • Cite this