Molecular Inorganic Silicon Chemistry: Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides

C. Krempner; H. Reinke; K. Weichert

doi:10.1002/9783527618224.ch2c

Molecular Inorganic Silicon Chemistry: Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides

C. Krempner, H. Reinke, K. Weichert

Chemistry and Biochemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

The bidentate metal disiloxides of general formula LMC1₂ [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me₃Si)₂HOSi-SiMe₂-SiOH(SiMe₂)[LH₂] (1) with M(NEt₂)₄ and subsequent addition of MCl₄ (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.

Original language	English
Title of host publication	Organosilicon Chemistry VI
Subtitle of host publication	From Molecules to Materials
Publisher	Wiley-VCH Verlag GmbH
Pages	344-347
Number of pages	4
ISBN (Print)	3527312145, 9783527312146
DOIs	https://doi.org/10.1002/9783527618224.ch2c
State	Published - May 21 2008

Keywords

Silanol
Silicon
Siloxide
Titanium
Zirconium

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10.1002/9783527618224.ch2c

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title = "Molecular Inorganic Silicon Chemistry: Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides",

abstract = "The bidentate metal disiloxides of general formula LMC12 [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me3Si)2HOSi-SiMe2-SiOH(SiMe2)[LH2] (1) with M(NEt2)4 and subsequent addition of MCl4 (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.",

keywords = "Silanol, Silicon, Siloxide, Titanium, Zirconium",

author = "C. Krempner and H. Reinke and K. Weichert",

year = "2008",

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doi = "10.1002/9783527618224.ch2c",

language = "English",

isbn = "3527312145",

pages = "344--347",

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TY - CHAP

T1 - Molecular Inorganic Silicon Chemistry

T2 - Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides

AU - Krempner, C.

AU - Reinke, H.

AU - Weichert, K.

PY - 2008/5/21

Y1 - 2008/5/21

N2 - The bidentate metal disiloxides of general formula LMC12 [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me3Si)2HOSi-SiMe2-SiOH(SiMe2)[LH2] (1) with M(NEt2)4 and subsequent addition of MCl4 (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.

AB - The bidentate metal disiloxides of general formula LMC12 [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me3Si)2HOSi-SiMe2-SiOH(SiMe2)[LH2] (1) with M(NEt2)4 and subsequent addition of MCl4 (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.

KW - Silanol

KW - Silicon

KW - Siloxide

KW - Titanium

KW - Zirconium

UR - http://www.scopus.com/inward/record.url?scp=84889825079&partnerID=8YFLogxK

U2 - 10.1002/9783527618224.ch2c

DO - 10.1002/9783527618224.ch2c

M3 - Chapter

AN - SCOPUS:84889825079

SN - 3527312145

SN - 9783527312146

SP - 344

EP - 347

BT - Organosilicon Chemistry VI

PB - Wiley-VCH Verlag GmbH

ER -

Molecular Inorganic Silicon Chemistry: Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides

Abstract

Keywords

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