Abstract
The bidentate metal disiloxides of general formula LMC12 [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me3Si)2HOSi-SiMe2-SiOH(SiMe2)[LH2] (1) with M(NEt2)4 and subsequent addition of MCl4 (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.
Original language | English |
---|---|
Title of host publication | Organosilicon Chemistry VI |
Subtitle of host publication | From Molecules to Materials |
Publisher | Wiley-VCH Verlag GmbH |
Pages | 344-347 |
Number of pages | 4 |
ISBN (Print) | 3527312145, 9783527312146 |
DOIs | |
State | Published - May 21 2008 |
Keywords
- Silanol
- Silicon
- Siloxide
- Titanium
- Zirconium