Molecular Inorganic Silicon Chemistry: Synthesis, Structure, and Reactivity of Novel Bidentate Metal Disiloxides

C. Krempner, H. Reinke, K. Weichert

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

Abstract

The bidentate metal disiloxides of general formula LMC12 [M = Ti, Zr; L = (1)-2H] (3) were readily prepared from the reaction of (Me3Si)2HOSi-SiMe2-SiOH(SiMe2)[LH2] (1) with M(NEt2)4 and subsequent addition of MCl4 (M = Ti, Zr), respectively. The solid-state structures of 3 were determined by X-ray crystallography.

Original languageEnglish
Title of host publicationOrganosilicon Chemistry VI
Subtitle of host publicationFrom Molecules to Materials
PublisherWiley-VCH Verlag GmbH
Pages344-347
Number of pages4
ISBN (Print)3527312145, 9783527312146
DOIs
StatePublished - May 21 2008

Keywords

  • Silanol
  • Silicon
  • Siloxide
  • Titanium
  • Zirconium

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