Modeling of the solid state interactions during lithium intercalation

Frédéric Vitse, Gerardine G. Botte

Research output: Contribution to conferencePaperpeer-review


Solid-state interaction forces between lithium ions and between lithium ion and several substrates during intercalation were investigated. At first, equations were derived, which provide the activity term representative of the interaction forces from experimental data of the open-circuit potential (OCV). Then, the sensitivity of the activity term to the statistically fitted data was discussed. A systematic procedure for the determination of the solid-state interaction forces during lithium intercalation was proposed and applied to lithium intercalation in a single spherical particle of Mn 2O 4.

Original languageEnglish
Number of pages8
StatePublished - 2004
Event205th Electrochemical Society Fall Meeting - Orlando, FL, United States
Duration: Oct 12 2003Oct 16 2003


Conference205th Electrochemical Society Fall Meeting
Country/TerritoryUnited States
CityOrlando, FL


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