Modeling of the solid state interactions during lithium intercalation

Frédéric Vitse; Gerardine G. Botte

Modeling of the solid state interactions during lithium intercalation

Chemical Engineering

Research output: Contribution to conference › Paper › peer-review

Abstract

Solid-state interaction forces between lithium ions and between lithium ion and several substrates during intercalation were investigated. At first, equations were derived, which provide the activity term representative of the interaction forces from experimental data of the open-circuit potential (OCV). Then, the sensitivity of the activity term to the statistically fitted data was discussed. A systematic procedure for the determination of the solid-state interaction forces during lithium intercalation was proposed and applied to lithium intercalation in a single spherical particle of Mn ₂O ₄.

Original language	English
Pages	287-294
Number of pages	8
State	Published - 2004
Event	205th Electrochemical Society Fall Meeting - Orlando, FL, United States Duration: Oct 12 2003 → Oct 16 2003

Conference

Conference	205th Electrochemical Society Fall Meeting
Country/Territory	United States
City	Orlando, FL
Period	10/12/03 → 10/16/03

Cite this

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title = "Modeling of the solid state interactions during lithium intercalation",

abstract = "Solid-state interaction forces between lithium ions and between lithium ion and several substrates during intercalation were investigated. At first, equations were derived, which provide the activity term representative of the interaction forces from experimental data of the open-circuit potential (OCV). Then, the sensitivity of the activity term to the statistically fitted data was discussed. A systematic procedure for the determination of the solid-state interaction forces during lithium intercalation was proposed and applied to lithium intercalation in a single spherical particle of Mn 2O 4.",

author = "Fr{\'e}d{\'e}ric Vitse and Botte, {Gerardine G.}",

year = "2004",

language = "English",

pages = "287--294",

note = "205th Electrochemical Society Fall Meeting ; Conference date: 12-10-2003 Through 16-10-2003",

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T1 - Modeling of the solid state interactions during lithium intercalation

AU - Vitse, Frédéric

AU - Botte, Gerardine G.

PY - 2004

Y1 - 2004

N2 - Solid-state interaction forces between lithium ions and between lithium ion and several substrates during intercalation were investigated. At first, equations were derived, which provide the activity term representative of the interaction forces from experimental data of the open-circuit potential (OCV). Then, the sensitivity of the activity term to the statistically fitted data was discussed. A systematic procedure for the determination of the solid-state interaction forces during lithium intercalation was proposed and applied to lithium intercalation in a single spherical particle of Mn 2O 4.

AB - Solid-state interaction forces between lithium ions and between lithium ion and several substrates during intercalation were investigated. At first, equations were derived, which provide the activity term representative of the interaction forces from experimental data of the open-circuit potential (OCV). Then, the sensitivity of the activity term to the statistically fitted data was discussed. A systematic procedure for the determination of the solid-state interaction forces during lithium intercalation was proposed and applied to lithium intercalation in a single spherical particle of Mn 2O 4.

UR - http://www.scopus.com/inward/record.url?scp=33645304828&partnerID=8YFLogxK

M3 - Paper

AN - SCOPUS:33645304828

SP - 287

EP - 294

T2 - 205th Electrochemical Society Fall Meeting

Y2 - 12 October 2003 through 16 October 2003

ER -

Modeling of the solid state interactions during lithium intercalation

Abstract

Conference

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