Mixture model description of the T-, P dependence of the refractive index of water

C. H. Cho; J. Urquidi; Gregory I. Gellene; G. Wilse Robinson

doi:10.1063/1.1331571

Mixture model description of the T-, P dependence of the refractive index of water

C. H. Cho, J. Urquidi, Gregory I. Gellene, G. Wilse Robinson

Chemistry and Biochemistry

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Abstract

The analysis of temperature and pressure dependence of refractive index of liquid water is presented. The two-state outer-neighbour mixed bonding structural model was utilized for the analysis. The high accuracy of refractive index measurements were used to test the structural model. Simple linear dependence of refractive temperature and pressure of the components of the two-state model was in agreement with the experimental refractive index data. The pressure dependence allowed the calculation of the isothermal piezo-optic coefficient as a function of temperature.

Original language	English
Pages (from-to)	3157-3162
Number of pages	6
Journal	Journal of Chemical Physics
Volume	114
Issue number	7
DOIs	https://doi.org/10.1063/1.1331571
State	Published - 2001

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abstract = "The analysis of temperature and pressure dependence of refractive index of liquid water is presented. The two-state outer-neighbour mixed bonding structural model was utilized for the analysis. The high accuracy of refractive index measurements were used to test the structural model. Simple linear dependence of refractive temperature and pressure of the components of the two-state model was in agreement with the experimental refractive index data. The pressure dependence allowed the calculation of the isothermal piezo-optic coefficient as a function of temperature.",

author = "Cho, {C. H.} and J. Urquidi and Gellene, {Gregory I.} and {Wilse Robinson}, G.",

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AU - Gellene, Gregory I.

AU - Wilse Robinson, G.

PY - 2001

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AB - The analysis of temperature and pressure dependence of refractive index of liquid water is presented. The two-state outer-neighbour mixed bonding structural model was utilized for the analysis. The high accuracy of refractive index measurements were used to test the structural model. Simple linear dependence of refractive temperature and pressure of the components of the two-state model was in agreement with the experimental refractive index data. The pressure dependence allowed the calculation of the isothermal piezo-optic coefficient as a function of temperature.

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M3 - Article

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JF - The Journal of Chemical Physics

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Mixture model description of the T-, P dependence of the refractive index of water

Abstract

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