Metal–Metal Double-Bond Formation and Control of Cluster Geometry via Steric Design: Syntheses and Structures of the First Ir4 Arsenido and Phosphido Complexes: Planar Unsaturated [Ir(μ-t-Bu2As)]4(μ-CO)2(CO)2(Ir=Ir) and Tetrahedral Saturated [Ir(μ-Cy2P)CO]4(μ-CO)2(Cy = Cyclohexyl)

Atta M. Arif, Richard A. Jones, Stuart T. Schwab, Bruce R. Whittlesey

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