Metal–Metal Double-Bond Formation and Control of Cluster Geometry via Steric Design: Syntheses and Structures of the First Ir4 Arsenido and Phosphido Complexes: Planar Unsaturated [Ir(μ-t-Bu2As)]4(μ-CO)2(CO)2(Ir=Ir) and Tetrahedral Saturated [Ir(μ-Cy2P)CO]4(μ-CO)2(Cy = Cyclohexyl)

Atta M. Arif, Richard A. Jones, Stuart T. Schwab, Bruce R. Whittlesey

Research output: Contribution to journalArticlepeer-review

18 Scopus citations
Original languageEnglish
Pages (from-to)1703-1705
Number of pages3
JournalJournal of the American Chemical Society
Volume108
Issue number7
DOIs
StatePublished - 1986

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Dive into the research topics of 'Metal–Metal Double-Bond Formation and Control of Cluster Geometry via Steric Design: Syntheses and Structures of the First Ir<sub>4</sub> Arsenido and Phosphido Complexes: Planar Unsaturated [Ir(μ-t-Bu<sub>2</sub>As)]<sub>4</sub>(μ-CO)<sub>2</sub>(CO)<sub>2</sub>(Ir=Ir) and Tetrahedral Saturated [Ir(μ-Cy<sub>2</sub>P)CO]<sub>4</sub>(μ-CO)<sub>2</sub>(Cy = Cyclohexyl)'. Together they form a unique fingerprint.

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