@article{3dee40bf975e42198de5a8423ffc17a0,
title = "Metal-free C(sp(3))-H functionalization: oxidative carbo-oxygenation of alpha-diazo carbonyls via radical dediazotization: Oxidative carbo-oxygenation of α-diazo carbonyls: Via radical dediazotization",
abstract = "A novel three-component carbo-oxygenation of alpha-diazo carbonyls for flexible synthesis of unprecedented alpha-aminooxy-beta-amino ketones has been established through metal-free C(sp(3))-H functionalization from readily accessible N,N-dimethylanilines and N-hydroxyphthalimide. The reaction pathway involves an in situ-generated phthalimide N-oxyl radical-triggered dediazotization/radical coupling sequence, leading to C-O and C-C bond formation.",
author = "Nan-Nan Wang and Wen-Juan Hao and Tian-Shu Zhang and Guigen Li and Ya-Nan Wu and Shu-Jiang Tu and Bo Jiang",
note = "Funding Information: We are grateful for financial support from the NSFC (No. 21232004, 21332005, and 21472071), PAPD of Jiangsu Higher Education Institutions, Robert A. Welch Foundation (D-1361, USA) and NIH (R33DA031860, USA), the Outstanding Youth Fund of JSNU (YQ2015003), NSF of Jiangsu Province (BK20151163), and the Open Foundation of Jiangsu Key Laboratory (K201505). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2016.",
year = "2016",
doi = "10.1039/c6cc00816j",
language = "English",
volume = "52",
pages = "5144--5147",
journal = "Chemical Communications",
issn = "1359-7345",
publisher = "Royal Society of Chemistry (RSC)",
number = "29",
}