Magnetic and Optical Properties of NaGdF4:Nd3+, Yb3+, Tm3+ Nanocrystals with Upconversion/Downconversion Luminescence from Visible to the Near-Infrared Second Window

Xianwen Zhang, Zhi Zhao, Xin Zhang, Brandon Weeks, Bensheng Qiu, Kailasnath Madanan, Dhiraj Sardar, Jhama Chaudhuri

Research output: Contribution to journalArticle

Abstract

We have designed and synthesized NaGdF4:Nd3+, Yb3+, Tm3+ magnetic nanophosphors with combined dual-mode downconversion (DC) and upconversion (UC) photoluminescence upon 800 nm excitation. Hexagonal-phase NaGdF4:Nd3+, Yb3+, Tm3+ nanocrystals (NCs) with an average size of 21 nm were synthesized using a solvothermal approach. Nd3+, Yb3+, Tm3+ triple-doped NaGdF4 NCs exhibit a broad range of photoluminescence peaks covering a near infrared first/second window (860-900, 1,000, and 1,060 nm), and visible emission including blue (475 nm), green (520 and 542 nm) and yellow (587 nm) after excitation at 800 nm. A mechanism involving circulation of energy over Gd3+ sublattices as bridge ions and final trapping by the initial activator ions (Nd3+) has been proposed. Penetration depth studies indicate that NIR emission is easily detected even at a large tissue thickness of 10 mm. These paramagnetic nanophosphors demonstrate a large magnetization value of 1.88 emu/g at 20 kOe and longitudinal relax
Original languageEnglish
Pages (from-to)636-648
JournalNano Research
DOIs
StatePublished - Feb 2015

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