Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems

Chau‐Chyun ‐C Chen; H. I. Britt; J. F. Boston; L. B. Evans

doi:10.1002/aic.690280410

Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems

Chau‐Chyun ‐C Chen, H. I. Britt, J. F. Boston, L. B. Evans

Chemical Engineering

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Abstract

An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.

Original language	English
Pages (from-to)	588-596
Number of pages	9
Journal	AIChE Journal
Volume	28
Issue number	4
DOIs	https://doi.org/10.1002/aic.690280410
State	Published - Jul 1982

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abstract = "An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.",

author = "Chen, {Chau‐Chyun ‐C} and Britt, {H. I.} and Boston, {J. F.} and Evans, {L. B.}",

year = "1982",

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AU - Boston, J. F.

AU - Evans, L. B.

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AB - An electrolyte local composition model is developed for excess Gibbs energy, which is assumed to be the sum of two contributions, one resulting from long range electrostatic forces between ions and the other from short range forces between all the species. The validity of the model is demonstrated for systems emcompassing the entire range from molecular liquid to fused salt.

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Local composition model for excess Gibbs energy of electrolyte systems. Part I: Single solvent, single completely dissociated electrolyte systems

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