Liquid viscosity model for polymer solutions and mixtures

Yuhua Song; Paul M. Mathias; David Tremblay; Chau Chyun Chen

doi:10.1021/ie030023x

Liquid viscosity model for polymer solutions and mixtures

Yuhua Song, Paul M. Mathias, David Tremblay, Chau Chyun Chen

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

A simple liquid viscosity model for multicomponent mixtures containing polymers is presented. This model is essentially a new mixing rule for calculating the Newtonian viscosity of mixtures over the entire composition range using the pure-component viscosities. A modified MarkHouwink model is applied to calculate the Newtonian viscosity of pure polymer melts, and the Andrade/DIPPR correlation model is used to calculate the viscosity of pure conventional components. Two binary parameters, one symmetric and one antisymmetric, are introduced to capture nonideal mixing behavior of Newtonian viscosity in polymer solutions. Applications to polystyrene solutions and poly(ethylene glycol) solutions are presented.

Original language	English
Pages (from-to)	2415-2422
Number of pages	8
Journal	Industrial and Engineering Chemistry Research
Volume	42
Issue number	11
DOIs	https://doi.org/10.1021/ie030023x
State	Published - May 28 2003

Access to Document

10.1021/ie030023x

Cite this

@article{30eee1617c834609bf1eb6082a58ba19,

title = "Liquid viscosity model for polymer solutions and mixtures",

abstract = "A simple liquid viscosity model for multicomponent mixtures containing polymers is presented. This model is essentially a new mixing rule for calculating the Newtonian viscosity of mixtures over the entire composition range using the pure-component viscosities. A modified MarkHouwink model is applied to calculate the Newtonian viscosity of pure polymer melts, and the Andrade/DIPPR correlation model is used to calculate the viscosity of pure conventional components. Two binary parameters, one symmetric and one antisymmetric, are introduced to capture nonideal mixing behavior of Newtonian viscosity in polymer solutions. Applications to polystyrene solutions and poly(ethylene glycol) solutions are presented.",

author = "Yuhua Song and Mathias, {Paul M.} and David Tremblay and Chen, {Chau Chyun}",

year = "2003",

month = may,

day = "28",

doi = "10.1021/ie030023x",

language = "English",

volume = "42",

pages = "2415--2422",

journal = "Industrial and Engineering Chemistry Research",

issn = "0888-5885",

number = "11",

}

TY - JOUR

T1 - Liquid viscosity model for polymer solutions and mixtures

AU - Song, Yuhua

AU - Mathias, Paul M.

AU - Tremblay, David

AU - Chen, Chau Chyun

PY - 2003/5/28

Y1 - 2003/5/28

N2 - A simple liquid viscosity model for multicomponent mixtures containing polymers is presented. This model is essentially a new mixing rule for calculating the Newtonian viscosity of mixtures over the entire composition range using the pure-component viscosities. A modified MarkHouwink model is applied to calculate the Newtonian viscosity of pure polymer melts, and the Andrade/DIPPR correlation model is used to calculate the viscosity of pure conventional components. Two binary parameters, one symmetric and one antisymmetric, are introduced to capture nonideal mixing behavior of Newtonian viscosity in polymer solutions. Applications to polystyrene solutions and poly(ethylene glycol) solutions are presented.

AB - A simple liquid viscosity model for multicomponent mixtures containing polymers is presented. This model is essentially a new mixing rule for calculating the Newtonian viscosity of mixtures over the entire composition range using the pure-component viscosities. A modified MarkHouwink model is applied to calculate the Newtonian viscosity of pure polymer melts, and the Andrade/DIPPR correlation model is used to calculate the viscosity of pure conventional components. Two binary parameters, one symmetric and one antisymmetric, are introduced to capture nonideal mixing behavior of Newtonian viscosity in polymer solutions. Applications to polystyrene solutions and poly(ethylene glycol) solutions are presented.

UR - http://www.scopus.com/inward/record.url?scp=0037503175&partnerID=8YFLogxK

U2 - 10.1021/ie030023x

DO - 10.1021/ie030023x

M3 - Article

AN - SCOPUS:0037503175

SN - 0888-5885

VL - 42

SP - 2415

EP - 2422

JO - Industrial and Engineering Chemistry Research

JF - Industrial and Engineering Chemistry Research

IS - 11

ER -

Liquid viscosity model for polymer solutions and mixtures

Abstract

Access to Document

Other files and links

Fingerprint

Cite this