@article{87df364b24d7494396e8dd442272c733,
title = "Ligand-Enabled δ-C(sp3)−H Borylation of Aliphatic Amines",
abstract = "Directed C−H functionalization has been realized as a complimentary technique to achieve borylation at a distal position of aliphatic amines. Here, we demonstrated the oxidative borylation at the distal δ-position of aliphatic amines using various borylating agents, a palladium catalyst, and a rightly tuned ligand in the presence of a cheap oxidant. Moreover, an organopalladium δ-C(sp3)-H-activated intermediate has been isolated and crystallographically characterized to get mechanistic insight.",
keywords = "C−H activation, Pd catalysis, mechanistic studies, δ-borylation",
author = "Chandrashekar, {Hediyala B.} and Pravas Dolui and Bijin Li and Astam Mandal and Hao Liu and Srimanta Guin and Haibo Ge and Debabrata Maiti",
note = "Funding Information: We thank SERB India (CRG/2018/003915), the Hongshen Young Scholars Program from Chongqing University (0247001104426), and the b. Chongqing Youth Top Talent Program (CQYC20200533) for financial support. Fellowship support for H.B.C. and P.D (UGC) and for A.M (CSIR) are humbly acknowledged. We would also like to acknowledge NSF (CHE‐2029932), Robert A. Welch Foundation (D2034‐20200401), and Texas Tech University for financial support. Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",
year = "2021",
month = aug,
day = "9",
doi = "10.1002/anie.202105204",
language = "English",
volume = "60",
pages = "18194--18200",
journal = "Angewandte Chemie - International Edition",
issn = "1433-7851",
number = "33",
}