Lewis acid base chemistry of Bestmann's ylide, Ph3PCCO, and its bulkier analogue, (cyclohexyl)3PCCO

Amandeep Brar; Daniel K. Unruh; Adelia J. Aquino; Clemens Krempner

doi:10.1039/c9cc01239g

Lewis acid base chemistry of Bestmann's ylide, Ph₃PCCO, and its bulkier analogue, (cyclohexyl)₃PCCO

Amandeep Brar, Daniel K. Unruh, Adelia J. Aquino, Clemens Krempner

Chemistry and Biochemistry

Research output: Contribution to journal › Article

2 Scopus citations

Abstract

The new phosphoranylideneketene, (cyclohexyl)₃PCCO, was synthesized and structurally as well as spectroscopically characterized. Ph₃PCCO and (cyclohexyl)₃PCCO were found to be weak ambidentate Lewis bases capable of donating to strong Lewis acids via the ylidic carbon or the carbonyl oxygen.

Original language	English
Pages (from-to)	3513-3516
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	24
DOIs	https://doi.org/10.1039/c9cc01239g
State	Published - 2019

Access to Document

10.1039/c9cc01239g

Link to publication in Scopus

Fingerprint Dive into the research topics of 'Lewis acid base chemistry of Bestmann's ylide, Ph<sub>3</sub>PCCO, and its bulkier analogue, (cyclohexyl)<sub>3</sub>PCCO'. Together they form a unique fingerprint.

Cite this

Brar, A., Unruh, D. K., Aquino, A. J., & Krempner, C. (2019). Lewis acid base chemistry of Bestmann's ylide, Ph₃PCCO, and its bulkier analogue, (cyclohexyl)₃PCCO. Chemical Communications, 55(24), 3513-3516. https://doi.org/10.1039/c9cc01239g

@article{e4e96fa719894eb795acaead4aa84150,

title = "Lewis acid base chemistry of Bestmann's ylide, Ph3PCCO, and its bulkier analogue, (cyclohexyl)3PCCO",

abstract = "The new phosphoranylideneketene, (cyclohexyl)3PCCO, was synthesized and structurally as well as spectroscopically characterized. Ph3PCCO and (cyclohexyl)3PCCO were found to be weak ambidentate Lewis bases capable of donating to strong Lewis acids via the ylidic carbon or the carbonyl oxygen.",

author = "Amandeep Brar and Unruh, {Daniel K.} and Aquino, {Adelia J.} and Clemens Krempner",

year = "2019",

doi = "10.1039/c9cc01239g",

language = "English",

volume = "55",

pages = "3513--3516",

journal = "Chemical Communications",

issn = "1359-7345",

number = "24",

}

TY - JOUR

T1 - Lewis acid base chemistry of Bestmann's ylide, Ph3PCCO, and its bulkier analogue, (cyclohexyl)3PCCO

AU - Brar, Amandeep

AU - Unruh, Daniel K.

AU - Aquino, Adelia J.

AU - Krempner, Clemens

PY - 2019

Y1 - 2019

N2 - The new phosphoranylideneketene, (cyclohexyl)3PCCO, was synthesized and structurally as well as spectroscopically characterized. Ph3PCCO and (cyclohexyl)3PCCO were found to be weak ambidentate Lewis bases capable of donating to strong Lewis acids via the ylidic carbon or the carbonyl oxygen.

AB - The new phosphoranylideneketene, (cyclohexyl)3PCCO, was synthesized and structurally as well as spectroscopically characterized. Ph3PCCO and (cyclohexyl)3PCCO were found to be weak ambidentate Lewis bases capable of donating to strong Lewis acids via the ylidic carbon or the carbonyl oxygen.

UR - http://www.scopus.com/inward/record.url?scp=85063088208&partnerID=8YFLogxK

U2 - 10.1039/c9cc01239g

DO - 10.1039/c9cc01239g

M3 - Article

C2 - 30839037

AN - SCOPUS:85063088208

VL - 55

SP - 3513

EP - 3516

JO - Chemical Communications

JF - Chemical Communications

SN - 1359-7345

IS - 24

ER -