K2CO3/Ni(OAc)2 catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source

Sheng Chen, Jian Lin Han, Gui Gen Li, Yi Pan

Research output: Contribution to journalArticle

Abstract

An efficient and facile aminobromination reaction ofβ-methyl-β-nitrostyrenes with PhCONH2/PhCONBr2 as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.

Original languageEnglish
Pages (from-to)213-219
Number of pages7
JournalChinese Journal of Inorganic Chemistry
Volume30
Issue number1
DOIs
StatePublished - Mar 4 2014

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Keywords

  • Aminobromination
  • Benzamide
  • Haloamines
  • β-methyl-β-nitrostyrenes

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