K2CO3/Ni(OAc)2 catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source

Sheng Chen; Jian Lin Han; Gui Gen Li; Yi Pan

doi:10.11862/CJIC.2014.042

K₂CO₃/Ni(OAc)₂ catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source

Sheng Chen, Jian Lin Han, Gui Gen Li, Yi Pan

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

An efficient and facile aminobromination reaction ofβ-methyl-β-nitrostyrenes with PhCONH₂/PhCONBr₂ as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.

Original language	English
Pages (from-to)	213-219
Number of pages	7
Journal	Chinese Journal of Inorganic Chemistry
Volume	30
Issue number	1
DOIs	https://doi.org/10.11862/CJIC.2014.042
State	Published - 2014

Keywords

Aminobromination
Benzamide
Haloamines
β-methyl-β-nitrostyrenes

Access to Document

10.11862/CJIC.2014.042

Cite this

@article{7f9e314479a1476084b4e98184fec951,

title = "K2CO3/Ni(OAc)2 catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source",

abstract = "An efficient and facile aminobromination reaction ofβ-methyl-β-nitrostyrenes with PhCONH2/PhCONBr2 as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.",

keywords = "Aminobromination, Benzamide, Haloamines, β-methyl-β-nitrostyrenes",

author = "Sheng Chen and Han, {Jian Lin} and Li, {Gui Gen} and Yi Pan",

year = "2014",

doi = "10.11862/CJIC.2014.042",

language = "English",

volume = "30",

pages = "213--219",

journal = "Chinese Journal of Inorganic Chemistry",

issn = "1001-4861",

number = "1",

}

TY - JOUR

T1 - K2CO3/Ni(OAc)2 catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source

AU - Chen, Sheng

AU - Han, Jian Lin

AU - Li, Gui Gen

AU - Pan, Yi

PY - 2014

Y1 - 2014

N2 - An efficient and facile aminobromination reaction ofβ-methyl-β-nitrostyrenes with PhCONH2/PhCONBr2 as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.

AB - An efficient and facile aminobromination reaction ofβ-methyl-β-nitrostyrenes with PhCONH2/PhCONBr2 as nitrogen/bromine source has been developed, which could tolerate a wide scope of substrates with good chemical yield and diastereoselectivity. This aminobrominaiton system uses metal salt and base as the co-catalyst, which is different from our previous reported systems.

KW - Aminobromination

KW - Benzamide

KW - Haloamines

KW - β-methyl-β-nitrostyrenes

UR - http://www.scopus.com/inward/record.url?scp=84894639142&partnerID=8YFLogxK

U2 - 10.11862/CJIC.2014.042

DO - 10.11862/CJIC.2014.042

M3 - Article

AN - SCOPUS:84894639142

SN - 1001-4861

VL - 30

SP - 213

EP - 219

JO - Chinese Journal of Inorganic Chemistry

JF - Chinese Journal of Inorganic Chemistry

IS - 1

ER -

K₂CO₃/Ni(OAc)₂ catalyzed aminobromination of β-methyl-β-nitrostyrenes with Benzamide/N,N-dibromobenzamide as nitrogen/bromine source

Abstract

Keywords

Access to Document

Other files and links

Fingerprint

Cite this