Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond

Nicholas J. Hill, Jennifer A. Moore, Michael Findlater, Alan H. Cowley

Research output: Contribution to journalArticle

Abstract

A 1 : 1 Lewis acid-base complex between CyN=C=NCy and PhBCl 2 has been isolated and structurally characterized, heating of which in refluxing toluene results in the amidinate, [PhC{NCy} 2 ]BCl 2 ; the overall reaction has been modeled by DFT calculations. © The Royal Society of Chemistry 2005.
Original languageEnglish
Pages (from-to)5462-5464
JournalChemical Communications
StatePublished - Nov 21 2005

Fingerprint Dive into the research topics of 'Isolation of an intermediate in the insertion of a carbodiimide into a boron-aryl bond'. Together they form a unique fingerprint.

  • Cite this