Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Pascal D.C. Dietzel; Peter A. Georgiev; Juergen Eckert; Richard Blom; Thierry Strässle; Tobias Unruh

doi:10.1039/c0cc00091d

Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M₂(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Pascal D.C. Dietzel, Peter A. Georgiev, Juergen Eckert, Richard Blom, Thierry Strässle, Tobias Unruh

Chemistry and Biochemistry

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143 Scopus citations

Abstract

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

Original language	English
Pages (from-to)	4962-4964
Number of pages	3
Journal	Chemical Communications
Volume	46
Issue number	27
DOIs	https://doi.org/10.1039/c0cc00091d
State	Published - 2010

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10.1039/c0cc00091d

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abstract = "Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.",

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AU - Blom, Richard

AU - Strässle, Thierry

AU - Unruh, Tobias

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