Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M2(dhtp) (CPO-27-M; M = Ni, Co, Mg)

Pascal D.C. Dietzel, Peter A. Georgiev, Juergen Eckert, Richard Blom, Thierry Strässle, Tobias Unruh

Research output: Contribution to journalArticle

143 Scopus citations

Abstract

Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.

Original languageEnglish
Pages (from-to)4962-4964
Number of pages3
JournalChemical Communications
Volume46
Issue number27
DOIs
StatePublished - 2010

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