Infrared spectroscopy in electrochemistry: New methods and connections to UhV surface science

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Abstract

This review discusses recent advances in the use of infrared spectroscopy in electrochemistry. The central focus is on analytical factors that affect the ability to derive structural information from infrared spectra of molecular adlayers. The effects of vibrational coupling and dielectric screening are emphasized. Applications of real-time polarization modulation and step-scan Fourier transform infrared spectroscopy are also presented.

Original languageEnglish
Pages (from-to)81-102
Number of pages22
JournalCritical Reviews in Analytical Chemistry
Volume27
Issue number2
DOIs
StatePublished - 1997

Keywords

  • electrochemistry
  • infrared spectroscopy
  • single crystal electrodes
  • surface chemistry
  • vibrational coupling

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