Inelastic neutron scattering study of the metal cluster compound Li6[Zr6Cl18H]

J. D. Corbett; J. Eckert; U. A. Jayasooriya; G. J. Kearley; R. P. White; J. Zhang

doi:10.1021/j100134a004

Inelastic neutron scattering study of the metal cluster compound Li₆[Zr₆Cl₁₈H]

J. D. Corbett, J. Eckert, U. A. Jayasooriya, G. J. Kearley, R. P. White, J. Zhang

Chemistry and Biochemistry

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Abstract

The optic modes of the hydrogen in the metal cluster compound Li₆[Zr₆Cl₁₈H] are observed at 480 and 790 cm^-1 using incoherent inelastic neutron scattering spectroscopy at ∼15 K, and confirmed using the spectrum of the deuterium substituted compound. This observation is rationalized in terms of a model with the hydrogen occupying a μ₃-bridging position within the octahedral interstitial site with a Zr-H bond distance of ca. 2.0 Å. The terminal and bridge bonded chlorine vibrations are observed at frequencies of ∼280 and ∼190 cm^-1, respectively.

Original language	English
Pages (from-to)	8384-8386
Number of pages	3
Journal	Journal of physical chemistry
Volume	97
Issue number	32
DOIs	https://doi.org/10.1021/j100134a004
State	Published - 1993

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title = "Inelastic neutron scattering study of the metal cluster compound Li6[Zr6Cl18H]",

abstract = "The optic modes of the hydrogen in the metal cluster compound Li6[Zr6Cl18H] are observed at 480 and 790 cm-1 using incoherent inelastic neutron scattering spectroscopy at ∼15 K, and confirmed using the spectrum of the deuterium substituted compound. This observation is rationalized in terms of a model with the hydrogen occupying a μ3-bridging position within the octahedral interstitial site with a Zr-H bond distance of ca. 2.0 {\AA}. The terminal and bridge bonded chlorine vibrations are observed at frequencies of ∼280 and ∼190 cm-1, respectively.",

author = "Corbett, {J. D.} and J. Eckert and Jayasooriya, {U. A.} and Kearley, {G. J.} and White, {R. P.} and J. Zhang",

year = "1993",

doi = "10.1021/j100134a004",

language = "English",

volume = "97",

pages = "8384--8386",

journal = "Journal of Physical Chemistry",

issn = "0022-3654",

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TY - JOUR

T1 - Inelastic neutron scattering study of the metal cluster compound Li6[Zr6Cl18H]

AU - Corbett, J. D.

AU - Eckert, J.

AU - Jayasooriya, U. A.

AU - Kearley, G. J.

AU - White, R. P.

AU - Zhang, J.

PY - 1993

Y1 - 1993

N2 - The optic modes of the hydrogen in the metal cluster compound Li6[Zr6Cl18H] are observed at 480 and 790 cm-1 using incoherent inelastic neutron scattering spectroscopy at ∼15 K, and confirmed using the spectrum of the deuterium substituted compound. This observation is rationalized in terms of a model with the hydrogen occupying a μ3-bridging position within the octahedral interstitial site with a Zr-H bond distance of ca. 2.0 Å. The terminal and bridge bonded chlorine vibrations are observed at frequencies of ∼280 and ∼190 cm-1, respectively.

AB - The optic modes of the hydrogen in the metal cluster compound Li6[Zr6Cl18H] are observed at 480 and 790 cm-1 using incoherent inelastic neutron scattering spectroscopy at ∼15 K, and confirmed using the spectrum of the deuterium substituted compound. This observation is rationalized in terms of a model with the hydrogen occupying a μ3-bridging position within the octahedral interstitial site with a Zr-H bond distance of ca. 2.0 Å. The terminal and bridge bonded chlorine vibrations are observed at frequencies of ∼280 and ∼190 cm-1, respectively.

UR - http://www.scopus.com/inward/record.url?scp=0040407632&partnerID=8YFLogxK

U2 - 10.1021/j100134a004

DO - 10.1021/j100134a004

M3 - Article

AN - SCOPUS:0040407632

SN - 0022-3654

VL - 97

SP - 8384

EP - 8386

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 32

ER -

Inelastic neutron scattering study of the metal cluster compound Li₆[Zr₆Cl₁₈H]

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