Abstract
Visible-light-induced catalytic hydrophosphonodifluoromethylation of mono- and disubstituted alkenes using bromodifluoromethanephosphonate with a Hantzsch ester as the terminal reductant is reported. The combination of thiyl-radical catalysis with photoredox catalysis is important for achieving good chemoselectivity and high yields.
Original language | English |
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Pages (from-to) | 578-587 |
Number of pages | 10 |
Journal | Journal of Organic Chemistry |
Volume | 83 |
Issue number | 2 |
DOIs | |
State | Published - Jan 19 2018 |