Highly reactive oligosilyltriflates - Synthesis, structure and rearrangement

C. Krempner; U. Jäger-Fiedler; C. Mamat; A. Spannenberg; K. Weichert

doi:10.1039/b408573f

Highly reactive oligosilyltriflates - Synthesis, structure and rearrangement

C. Krempner, U. Jäger-Fiedler, C. Mamat, A. Spannenberg, K. Weichert

Chemistry and Biochemistry

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Abstract

The novel branched oligosilyltriflates of formula [TfO(Me ₃Si)₂Si]₂E (2a-d) [E = 0 (2a), SiMe₂ (2b), GeMe₂ (2c), SiMe₂-SiMe₂ (2d)] and [TfO(Me₃Si)₂SiSiMe₂]SiMe (9) have been prepared by the protodesilylation of [Ph(Me₃Si)₂Si]₂E (1a-c), [H(Me₃Si)₂Si]₂E (5d) and [Ph(Me ₃Si)₂SiSiMe₂]₃SiMe (8) using TfOH (CF₃SO₃H) as reagent in almost quantitative yields. The crystal structure of 2b is reported.

Original language	English
Pages (from-to)	1581-1584
Number of pages	4
Journal	New Journal of Chemistry
Volume	29
Issue number	12
DOIs	https://doi.org/10.1039/b408573f
State	Published - Dec 2005

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title = "Highly reactive oligosilyltriflates - Synthesis, structure and rearrangement",

abstract = "The novel branched oligosilyltriflates of formula [TfO(Me 3Si)2Si]2E (2a-d) [E = 0 (2a), SiMe2 (2b), GeMe2 (2c), SiMe2-SiMe2 (2d)] and [TfO(Me3Si)2SiSiMe2]SiMe (9) have been prepared by the protodesilylation of [Ph(Me3Si)2Si]2E (1a-c), [H(Me3Si)2Si]2E (5d) and [Ph(Me 3Si)2SiSiMe2]3SiMe (8) using TfOH (CF3SO3H) as reagent in almost quantitative yields. The crystal structure of 2b is reported.",

author = "C. Krempner and U. J{\"a}ger-Fiedler and C. Mamat and A. Spannenberg and K. Weichert",

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language = "English",

volume = "29",

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T1 - Highly reactive oligosilyltriflates - Synthesis, structure and rearrangement

AU - Krempner, C.

AU - Jäger-Fiedler, U.

AU - Mamat, C.

AU - Spannenberg, A.

AU - Weichert, K.

PY - 2005/12

Y1 - 2005/12

N2 - The novel branched oligosilyltriflates of formula [TfO(Me 3Si)2Si]2E (2a-d) [E = 0 (2a), SiMe2 (2b), GeMe2 (2c), SiMe2-SiMe2 (2d)] and [TfO(Me3Si)2SiSiMe2]SiMe (9) have been prepared by the protodesilylation of [Ph(Me3Si)2Si]2E (1a-c), [H(Me3Si)2Si]2E (5d) and [Ph(Me 3Si)2SiSiMe2]3SiMe (8) using TfOH (CF3SO3H) as reagent in almost quantitative yields. The crystal structure of 2b is reported.

AB - The novel branched oligosilyltriflates of formula [TfO(Me 3Si)2Si]2E (2a-d) [E = 0 (2a), SiMe2 (2b), GeMe2 (2c), SiMe2-SiMe2 (2d)] and [TfO(Me3Si)2SiSiMe2]SiMe (9) have been prepared by the protodesilylation of [Ph(Me3Si)2Si]2E (1a-c), [H(Me3Si)2Si]2E (5d) and [Ph(Me 3Si)2SiSiMe2]3SiMe (8) using TfOH (CF3SO3H) as reagent in almost quantitative yields. The crystal structure of 2b is reported.

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U2 - 10.1039/b408573f

DO - 10.1039/b408573f

M3 - Article

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EP - 1584

JO - New Journal of Chemistry

JF - New Journal of Chemistry

SN - 1144-0546

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ER -

Highly reactive oligosilyltriflates - Synthesis, structure and rearrangement

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