Heterogeneous Reaction Kinetics of Epoxide-Functionalized Regenerated Cellulose Membrane and Aliphatic Amine

Yung P Koh; Muhammad Karim; Sindee Simon

doi:10.1016/j.tca.2012.04.031

Heterogeneous Reaction Kinetics of Epoxide-Functionalized Regenerated Cellulose Membrane and Aliphatic Amine

Yung P Koh, Muhammad Karim, Sindee Simon

Chemical Engineering

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction kinetics of an epoxide-functionalized regenerated cellulose membrane with excess aliphatic amine are examined using differential scanning calorimetry. Both isothermal and dynamic experiments are analyzed. The reaction is found to follow first-order autocatalytic kinetics. The activation energy based on five different methods ranges from 77.0 to 79.7 kJ/mol, indicating that the apparent activation energy for the heterogeneous epoxy/aliphatic amine reaction is considerably higher than the values reported in the literature for the homogeneous reaction.

Original language	English
Pages (from-to)	18 - 23
Journal	Thermochimica Acta
DOIs	https://doi.org/10.1016/j.tca.2012.04.031
State	Published - Sep 10 2012

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10.1016/j.tca.2012.04.031

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title = "Heterogeneous Reaction Kinetics of Epoxide-Functionalized Regenerated Cellulose Membrane and Aliphatic Amine",

abstract = "The reaction kinetics of an epoxide-functionalized regenerated cellulose membrane with excess aliphatic amine are examined using differential scanning calorimetry. Both isothermal and dynamic experiments are analyzed. The reaction is found to follow first-order autocatalytic kinetics. The activation energy based on five different methods ranges from 77.0 to 79.7 kJ/mol, indicating that the apparent activation energy for the heterogeneous epoxy/aliphatic amine reaction is considerably higher than the values reported in the literature for the homogeneous reaction.",

author = "Koh, {Yung P} and Muhammad Karim and Sindee Simon",

year = "2012",

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doi = "10.1016/j.tca.2012.04.031",

language = "English",

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journal = "Thermochimica Acta",

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AU - Koh, Yung P

AU - Karim, Muhammad

AU - Simon, Sindee

PY - 2012/9/10

Y1 - 2012/9/10

N2 - The reaction kinetics of an epoxide-functionalized regenerated cellulose membrane with excess aliphatic amine are examined using differential scanning calorimetry. Both isothermal and dynamic experiments are analyzed. The reaction is found to follow first-order autocatalytic kinetics. The activation energy based on five different methods ranges from 77.0 to 79.7 kJ/mol, indicating that the apparent activation energy for the heterogeneous epoxy/aliphatic amine reaction is considerably higher than the values reported in the literature for the homogeneous reaction.

AB - The reaction kinetics of an epoxide-functionalized regenerated cellulose membrane with excess aliphatic amine are examined using differential scanning calorimetry. Both isothermal and dynamic experiments are analyzed. The reaction is found to follow first-order autocatalytic kinetics. The activation energy based on five different methods ranges from 77.0 to 79.7 kJ/mol, indicating that the apparent activation energy for the heterogeneous epoxy/aliphatic amine reaction is considerably higher than the values reported in the literature for the homogeneous reaction.

U2 - 10.1016/j.tca.2012.04.031

DO - 10.1016/j.tca.2012.04.031

M3 - Article

SP - 18

EP - 23

JO - Thermochimica Acta

JF - Thermochimica Acta

ER -

Heterogeneous Reaction Kinetics of Epoxide-Functionalized Regenerated Cellulose Membrane and Aliphatic Amine

Abstract

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