General discussion

H. J. Loesch; J. S. Carley; L. Zandee; J. Reuss; R. J. Le Roy; M. S. Child; D. A. Dixon; D. R. Herschbach; W. Klemperer; R. J. Whitehead; S. Swaminathan; E. Guth; D. L. Beveridge; W. Kutzelnigg; J. N. Murrell; K. F. Freed; W. L. Hase; H. C. Longuet-Higgins; J. J.C. Mulder; F. Engelke; J. C. Whitehead; R. N. Zare; R. C. Estler; D. Lubman; T. F. George; Peter A. Gorry; Roger Grice; J. C. Polanyi; J. L. Schreiber; W. J. Skrlac; P. S. Bagus; G. Del Conde; D. W. Davies; I. H. Hillier; R. E. Wyatt; J. A. McNutt; S. L. Latham; M. J. Redmon; W. Jakubetz; J. N.L. Connor; S. J. Fraser; A. Komornicki; K. Morokuma; B. A. Blackwell; J. J. Sloan; S. R. Ungemach; H. F. Schaefer; B. Liu; D. E. Klimek; A. Ding; V. Aquilanti; G. Luiti; F. Pirani; F. Vecchiocattivi; G. G. Volpi; K. P. Lawley; J. Costello; M. A.D. Fluendy; M. J.S. Dewar

doi:10.1039/DC9776200300

General discussion

H. J. Loesch, J. S. Carley, L. Zandee, J. Reuss, R. J. Le Roy, M. S. Child, D. A. Dixon, D. R. Herschbach, W. Klemperer, R. J. Whitehead, S. Swaminathan, E. Guth, D. L. Beveridge, W. Kutzelnigg, J. N. Murrell, K. F. Freed, W. L. Hase, H. C. Longuet-Higgins, J. J.C. Mulder, F. EngelkeJ. C. Whitehead, R. N. Zare, R. C. Estler, D. Lubman, T. F. George, Peter A. Gorry, Roger Grice, J. C. Polanyi, J. L. Schreiber, W. J. Skrlac, P. S. Bagus, G. Del Conde, D. W. Davies, I. H. Hillier, R. E. Wyatt, J. A. McNutt, S. L. Latham, M. J. Redmon, W. Jakubetz, J. N.L. Connor, S. J. Fraser, A. Komornicki, K. Morokuma, B. A. Blackwell, J. J. Sloan, S. R. Ungemach, H. F. Schaefer, B. Liu, D. E. Klimek, A. Ding, V. Aquilanti, G. Luiti, F. Pirani, F. Vecchiocattivi, G. G. Volpi, K. P. Lawley, J. Costello, M. A.D. Fluendy, M. J.S. Dewar

Chemistry and Biochemistry

Research output: Contribution to journal › Comment/debate

Original language	English
Pages (from-to)	300-346
Number of pages	47
Journal	Faraday Discussions of the Chemical Society
Volume	62
DOIs	https://doi.org/10.1039/DC9776200300
State	Published - 1977

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10.1039/DC9776200300

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Loesch, H. J., Carley, J. S., Zandee, L., Reuss, J., Le Roy, R. J., Child, M. S., Dixon, D. A., Herschbach, D. R., Klemperer, W., Whitehead, R. J., Swaminathan, S., Guth, E., Beveridge, D. L., Kutzelnigg, W., Murrell, J. N., Freed, K. F., Hase, W. L., Longuet-Higgins, H. C., Mulder, J. J. C., ... Dewar, M. J. S. (1977). General discussion. Faraday Discussions of the Chemical Society, 62, 300-346. https://doi.org/10.1039/DC9776200300

Loesch, H. J. ; Carley, J. S. ; Zandee, L. ; Reuss, J. ; Le Roy, R. J. ; Child, M. S. ; Dixon, D. A. ; Herschbach, D. R. ; Klemperer, W. ; Whitehead, R. J. ; Swaminathan, S. ; Guth, E. ; Beveridge, D. L. ; Kutzelnigg, W. ; Murrell, J. N. ; Freed, K. F. ; Hase, W. L. ; Longuet-Higgins, H. C. ; Mulder, J. J.C. ; Engelke, F. ; Whitehead, J. C. ; Zare, R. N. ; Estler, R. C. ; Lubman, D. ; George, T. F. ; Gorry, Peter A. ; Grice, Roger ; Polanyi, J. C. ; Schreiber, J. L. ; Skrlac, W. J. ; Bagus, P. S. ; Del Conde, G. ; Davies, D. W. ; Hillier, I. H. ; Wyatt, R. E. ; McNutt, J. A. ; Latham, S. L. ; Redmon, M. J. ; Jakubetz, W. ; Connor, J. N.L. ; Fraser, S. J. ; Komornicki, A. ; Morokuma, K. ; Blackwell, B. A. ; Sloan, J. J. ; Ungemach, S. R. ; Schaefer, H. F. ; Liu, B. ; Klimek, D. E. ; Ding, A. ; Aquilanti, V. ; Luiti, G. ; Pirani, F. ; Vecchiocattivi, F. ; Volpi, G. G. ; Lawley, K. P. ; Costello, J. ; Fluendy, M. A.D. ; Dewar, M. J.S. / General discussion. In: Faraday Discussions of the Chemical Society. 1977 ; Vol. 62. pp. 300-346.

@article{7a80524d5a23421eaa9dbf08c090413a,

title = "General discussion",

author = "Loesch, {H. J.} and Carley, {J. S.} and L. Zandee and J. Reuss and {Le Roy}, {R. J.} and Child, {M. S.} and Dixon, {D. A.} and Herschbach, {D. R.} and W. Klemperer and Whitehead, {R. J.} and S. Swaminathan and E. Guth and Beveridge, {D. L.} and W. Kutzelnigg and Murrell, {J. N.} and Freed, {K. F.} and Hase, {W. L.} and Longuet-Higgins, {H. C.} and Mulder, {J. J.C.} and F. Engelke and Whitehead, {J. C.} and Zare, {R. N.} and Estler, {R. C.} and D. Lubman and George, {T. F.} and Gorry, {Peter A.} and Roger Grice and Polanyi, {J. C.} and Schreiber, {J. L.} and Skrlac, {W. J.} and Bagus, {P. S.} and {Del Conde}, G. and Davies, {D. W.} and Hillier, {I. H.} and Wyatt, {R. E.} and McNutt, {J. A.} and Latham, {S. L.} and Redmon, {M. J.} and W. Jakubetz and Connor, {J. N.L.} and Fraser, {S. J.} and A. Komornicki and K. Morokuma and Blackwell, {B. A.} and Sloan, {J. J.} and Ungemach, {S. R.} and Schaefer, {H. F.} and B. Liu and Klimek, {D. E.} and A. Ding and V. Aquilanti and G. Luiti and F. Pirani and F. Vecchiocattivi and Volpi, {G. G.} and Lawley, {K. P.} and J. Costello and Fluendy, {M. A.D.} and Dewar, {M. J.S.}",

note = "Funding Information: Further, our results suggest the need for more refined experimental and theoretical investigations. Experimentally, results based on a state selected spin-orbit state are needed to substantiate our predictions. Theoretically, our results suggest that a single surface treatment of this reaction may be incomplete even at low energies. We thank the donors of the Petroleum Research Fund, administered by the American Chemical Society, the Air Force Office of Scientific Research and the National Science Foundation for support. Miss B. A. Blackwell, Prof. J. C. Polanyi and Dr. J. J. Sloan (University of Toronto) said: There has been discussion of the fact that in a number of systems enhanced reagent vibration, <A V ) , tends to be channelled efficiently into enhanced product vibration, (AV{\textquoteright}).{\textquoteright}” This raises the intriguing possibility that a thermoneutral re- action (-AH,” = 0) could, with appropriate reagent vibrational excitation, give rise to highly vibrationally excited reaction products. ",

year = "1977",

doi = "10.1039/DC9776200300",

language = "English",

volume = "62",

pages = "300--346",

journal = "Faraday Discussions of the Chemical Society",

issn = "0301-7249",

}

Loesch, HJ, Carley, JS, Zandee, L, Reuss, J, Le Roy, RJ, Child, MS, Dixon, DA, Herschbach, DR, Klemperer, W, Whitehead, RJ, Swaminathan, S, Guth, E, Beveridge, DL, Kutzelnigg, W, Murrell, JN, Freed, KF, Hase, WL, Longuet-Higgins, HC, Mulder, JJC, Engelke, F, Whitehead, JC, Zare, RN, Estler, RC, Lubman, D, George, TF, Gorry, PA, Grice, R, Polanyi, JC, Schreiber, JL, Skrlac, WJ, Bagus, PS, Del Conde, G, Davies, DW, Hillier, IH, Wyatt, RE, McNutt, JA, Latham, SL, Redmon, MJ, Jakubetz, W, Connor, JNL, Fraser, SJ, Komornicki, A, Morokuma, K, Blackwell, BA, Sloan, JJ, Ungemach, SR, Schaefer, HF, Liu, B, Klimek, DE, Ding, A, Aquilanti, V, Luiti, G, Pirani, F, Vecchiocattivi, F, Volpi, GG, Lawley, KP, Costello, J, Fluendy, MAD & Dewar, MJS 1977, 'General discussion', Faraday Discussions of the Chemical Society, vol. 62, pp. 300-346. https://doi.org/10.1039/DC9776200300

General discussion. / Loesch, H. J.; Carley, J. S.; Zandee, L.; Reuss, J.; Le Roy, R. J.; Child, M. S.; Dixon, D. A.; Herschbach, D. R.; Klemperer, W.; Whitehead, R. J.; Swaminathan, S.; Guth, E.; Beveridge, D. L.; Kutzelnigg, W.; Murrell, J. N.; Freed, K. F.; Hase, W. L.; Longuet-Higgins, H. C.; Mulder, J. J.C.; Engelke, F.; Whitehead, J. C.; Zare, R. N.; Estler, R. C.; Lubman, D.; George, T. F.; Gorry, Peter A.; Grice, Roger; Polanyi, J. C.; Schreiber, J. L.; Skrlac, W. J.; Bagus, P. S.; Del Conde, G.; Davies, D. W.; Hillier, I. H.; Wyatt, R. E.; McNutt, J. A.; Latham, S. L.; Redmon, M. J.; Jakubetz, W.; Connor, J. N.L.; Fraser, S. J.; Komornicki, A.; Morokuma, K.; Blackwell, B. A.; Sloan, J. J.; Ungemach, S. R.; Schaefer, H. F.; Liu, B.; Klimek, D. E.; Ding, A.; Aquilanti, V.; Luiti, G.; Pirani, F.; Vecchiocattivi, F.; Volpi, G. G.; Lawley, K. P.; Costello, J.; Fluendy, M. A.D.; Dewar, M. J.S.

In: Faraday Discussions of the Chemical Society, Vol. 62, 1977, p. 300-346.

Research output: Contribution to journal › Comment/debate

TY - JOUR

T1 - General discussion

AU - Loesch, H. J.

AU - Carley, J. S.

AU - Zandee, L.

AU - Reuss, J.

AU - Le Roy, R. J.

AU - Child, M. S.

AU - Dixon, D. A.

AU - Herschbach, D. R.

AU - Klemperer, W.

AU - Whitehead, R. J.

AU - Swaminathan, S.

AU - Guth, E.

AU - Beveridge, D. L.

AU - Kutzelnigg, W.

AU - Murrell, J. N.

AU - Freed, K. F.

AU - Hase, W. L.

AU - Longuet-Higgins, H. C.

AU - Mulder, J. J.C.

AU - Engelke, F.

AU - Whitehead, J. C.

AU - Zare, R. N.

AU - Estler, R. C.

AU - Lubman, D.

AU - George, T. F.

AU - Gorry, Peter A.

AU - Grice, Roger

AU - Polanyi, J. C.

AU - Schreiber, J. L.

AU - Skrlac, W. J.

AU - Bagus, P. S.

AU - Del Conde, G.

AU - Davies, D. W.

AU - Hillier, I. H.

AU - Wyatt, R. E.

AU - McNutt, J. A.

AU - Latham, S. L.

AU - Redmon, M. J.

AU - Jakubetz, W.

AU - Connor, J. N.L.

AU - Fraser, S. J.

AU - Komornicki, A.

AU - Morokuma, K.

AU - Blackwell, B. A.

AU - Sloan, J. J.

AU - Ungemach, S. R.

AU - Schaefer, H. F.

AU - Liu, B.

AU - Klimek, D. E.

AU - Ding, A.

AU - Aquilanti, V.

AU - Luiti, G.

AU - Pirani, F.

AU - Vecchiocattivi, F.

AU - Volpi, G. G.

AU - Lawley, K. P.

AU - Costello, J.

AU - Fluendy, M. A.D.

AU - Dewar, M. J.S.

N1 - Funding Information: Further, our results suggest the need for more refined experimental and theoretical investigations. Experimentally, results based on a state selected spin-orbit state are needed to substantiate our predictions. Theoretically, our results suggest that a single surface treatment of this reaction may be incomplete even at low energies. We thank the donors of the Petroleum Research Fund, administered by the American Chemical Society, the Air Force Office of Scientific Research and the National Science Foundation for support. Miss B. A. Blackwell, Prof. J. C. Polanyi and Dr. J. J. Sloan (University of Toronto) said: There has been discussion of the fact that in a number of systems enhanced reagent vibration, <A V ) , tends to be channelled efficiently into enhanced product vibration, (AV’).’” This raises the intriguing possibility that a thermoneutral re- action (-AH,” = 0) could, with appropriate reagent vibrational excitation, give rise to highly vibrationally excited reaction products.

PY - 1977

Y1 - 1977

UR - http://www.scopus.com/inward/record.url?scp=37049094368&partnerID=8YFLogxK

U2 - 10.1039/DC9776200300

DO - 10.1039/DC9776200300

M3 - Comment/debate

AN - SCOPUS:37049094368

VL - 62

SP - 300

EP - 346

JO - Faraday Discussions of the Chemical Society

JF - Faraday Discussions of the Chemical Society

SN - 0301-7249

ER -

General discussion

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