Fractioning of isotopic species between coexisting liquid and vapor water. Complete temperature range, including the asymptotic critical behavior

M. L. Japas, R. Fernandez-Prini, J. Horita, D. J. Wesolowski

Research output: Contribution to journalArticle

27 Scopus citations

Abstract

Data for the fractionation of D/H and 18O/16O in water liquid-vapor equilibrium may be satisfactorily accounted for over the entire temperature range of coexistence with a rigorous thermodynamic relation and the assumption of ideal mixing of the binary isotopic water mixtures. D/H fractionation is used to clarify why the asymptotic behavior observed for many systems extends over a wide range of temperatures, but is very narrow for isotopic binary mixtures.

Original languageEnglish
Pages (from-to)5171-5175
Number of pages5
JournalJournal of physical chemistry
Volume99
Issue number14
DOIs
StatePublished - 1995

Fingerprint Dive into the research topics of 'Fractioning of isotopic species between coexisting liquid and vapor water. Complete temperature range, including the asymptotic critical behavior'. Together they form a unique fingerprint.

  • Cite this