TY - JOUR
T1 - Fast supercapacitors based on graphene-bridged V2O3/VOx core-shell nanostructure electrodes with a power density of 1 MW kg-1
AU - Pan, Xuan
AU - Ren, Guofeng
AU - Hoque, Md Nadim Ferdous
AU - Bayne, Stephen
AU - Zhu, Kai
AU - Fan, Zhaoyang
N1 - Publisher Copyright:
© 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
PY - 2014/12/1
Y1 - 2014/12/1
N2 - Transition metal oxides (TMOs), with their very large pseudocapacitance effect, hold promise for next generation high-energy-density electrochemical supercapacitors (ECs). However, the typical high resistivity of TMOs restricts the reported ECs to work at a low charge-discharge (C-D) rate of 0.1-1 V s-1. Here, a novel vanadium oxides core/shell nanostructure-based electrode to overcome the resistivity challenge of TMOs for rapid pseudocapacitive EC design is reported. Quasi-metallic V2O3 nanocores are dispersed on graphene sheets for electrical connection of the whole structure, while a naturally formed amorphous VO2 and V2O5 (called as VOx here) thin shell around V2O3 nanocore acts as the active pseudocapacitive material. With such a graphene-bridged V2O3/VOx core-shell composite as electrode material, ECs with a C-D rate as high as 50 V s-1 is demonstrated. This high rate was attributed to the largely enhanced conductivity of this unique structure and a possibly facile redox mechanism. Such an EC can provide 1000 kW kg-1 power density at an energy density of 10 Wh kg-1. At the critical 45° phase angle, these ECs have a measured frequency of 114 Hz. All these indicate the graphene-bridged V2O3/VOx core-shell structure is promising for fast EC development. A graphene-bridged V2O3/VOx core-shell nanostructure based supercapacitor demonstrates an extremely high charge-discharge rate (50 V s-1) and a high-power density performance. In this structure, quasi-metallic V2O3 nanocores are dispersed on graphene sheets for electrical connection of the whole structure, while a naturally formed amorphous VO2 and V2O5 (or VOx) thin shell around the V2O3 nanocore acts as the active pseudocapacitive material.
AB - Transition metal oxides (TMOs), with their very large pseudocapacitance effect, hold promise for next generation high-energy-density electrochemical supercapacitors (ECs). However, the typical high resistivity of TMOs restricts the reported ECs to work at a low charge-discharge (C-D) rate of 0.1-1 V s-1. Here, a novel vanadium oxides core/shell nanostructure-based electrode to overcome the resistivity challenge of TMOs for rapid pseudocapacitive EC design is reported. Quasi-metallic V2O3 nanocores are dispersed on graphene sheets for electrical connection of the whole structure, while a naturally formed amorphous VO2 and V2O5 (called as VOx here) thin shell around V2O3 nanocore acts as the active pseudocapacitive material. With such a graphene-bridged V2O3/VOx core-shell composite as electrode material, ECs with a C-D rate as high as 50 V s-1 is demonstrated. This high rate was attributed to the largely enhanced conductivity of this unique structure and a possibly facile redox mechanism. Such an EC can provide 1000 kW kg-1 power density at an energy density of 10 Wh kg-1. At the critical 45° phase angle, these ECs have a measured frequency of 114 Hz. All these indicate the graphene-bridged V2O3/VOx core-shell structure is promising for fast EC development. A graphene-bridged V2O3/VOx core-shell nanostructure based supercapacitor demonstrates an extremely high charge-discharge rate (50 V s-1) and a high-power density performance. In this structure, quasi-metallic V2O3 nanocores are dispersed on graphene sheets for electrical connection of the whole structure, while a naturally formed amorphous VO2 and V2O5 (or VOx) thin shell around the V2O3 nanocore acts as the active pseudocapacitive material.
KW - graphene
KW - high-power density
KW - hydrogen processing
KW - supercapacitor
KW - vanadium oxide
UR - http://www.scopus.com/inward/record.url?scp=84931289228&partnerID=8YFLogxK
U2 - 10.1002/admi.201400398
DO - 10.1002/admi.201400398
M3 - Article
AN - SCOPUS:84931289228
SN - 2196-7350
VL - 1
JO - Advanced Materials Interfaces
JF - Advanced Materials Interfaces
IS - 9
M1 - 1400398
ER -