Extremely Fragile Glass-Formers? Calorimetric and Rheological Determinations

Astrid Torres Arellano, Gregory McKenna

Research output: Contribution to journalArticlepeer-review


We use calorimetry and rheology to investigate reports of extremely fragile polymers and the speculation that d,l-lactic acid should be extremely fragile. The dynamic fragilities of lactic acid, polysulfone, bisphenol-A polycarbonate, and poly(vinyl chloride) were studied. The polymers were used as received and after a wash-precipitation treatment. The current dynamic fragility findings are not in agreement with those reported by C. Evans, H. Deng, W. Jager, J. Torkelson, Macromolecules2013, 46 (15), 6091-6103 of extremely high fragilities for the mentioned polymers. We also found no sample preparation history effect on the dynamic fragility values. The calorimetric and rheological results for the d,l-lactic acid show dynamic fragility values that are consistent with each other and are not extremely fragile. Calorimetric measurements that use a broad range of cooling rates gave smaller dynamic fragility values than those obtained from a limited range at higher cooling rates. The impor
Original languageEnglish
Pages (from-to)1261-1272
JournalJournal of Polymer Science Part B: Polymer Physics
StatePublished - Sep 2015


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