Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies

Dorina F. Sava, Victor Ch Kravtsov, Juergen Eckert, Jarrod F. Eubank, Farid Nouar, Mohamed Eddaoudi

Research output: Contribution to journalArticle

105 Scopus citations

Abstract

(Figure Presented) Herein we detail a novel approach for targeting zeolite-like metal-organic frameworks (ZMOFs) that utilizes metal-organic cubes, which are regarded as double four-membered rings (d4Rs) and are composite building units (BUs) in traditional inorganic zeolites. Accordingly, we outline the successful implementation of this strategy by reporting two ZMOFs with ACO and AST zeolite-like topologies, which were constructed from d4R BUs exclusively held together by hydrogen bonds. Their porosity was evaluated, delineating high hydrogen uptake and exceptional stability for the two hydrogen-bonded materials.

Original languageEnglish
Pages (from-to)10394-10396
Number of pages3
JournalJournal of the American Chemical Society
Volume131
Issue number30
DOIs
StatePublished - Aug 5 2009

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