Enhanced H2 adsorption enthalpy in the low-surface area, partially fluorinated coordination polymer Zn5(triazole) 6(tetrafluoroterephthalate)2(H2O) 2·4H2O

Zeric Hulvey, Eduardo H.L. Falcao, Juergen Eckert, Anthony K. Cheetham

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Abstract

A porous coordination polymer containing zinc, 1,2,4-triazolate, and tetrafluoroterephthalate displays a high physisorptive hydrogen adsorption enthalpy of 8 kJ/mol, as a result of fluorine atoms exposed to the pore surface and the structure's small pore size.

Original languageEnglish
Pages (from-to)4307-4309
Number of pages3
JournalJournal of Materials Chemistry
Volume19
Issue number25
DOIs
StatePublished - 2009

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