Energy transfer dynamics in the collision-induced dissociation of Al6 and Al13 clusters

Pascal De Sainte Claire, Gilles H. Peslherbe, William L. Hase

Research output: Contribution to journalArticlepeer-review

51 Scopus citations

Abstract

Using a model analytic potential energy function developed for Aln clusters [J. Chem. Phys. 1987, 87, 2205] and a UMP2(fc)/6-31G* potential derived here for the Ar-Al interaction, classical trajectory simulations are performed to study collision-induced dissociation (CID) of Al6 and Al13 with argon. For the octahedral Al6 (Oh) cluster the CID threshold is ∼14 kcal/mol higher than the true threshold. This is because, near the threshold, there are no trajectories which transfer all the reactant relative translational energy to Al6 internal energy. For the planar Al6 (C2h) cluster, the CID threshold is closer to the true threshold. For the spherically shaped Al6 (Oh) and Al13 (D3d) clusters, T → V is the predominant energy transfer pathway. T → R energy transfer is important for the planar Al6 (C2h), Al13 (D2h), and Al13 (D6h) clusters. T → V energy transfer is enhanced as the cluster is softened (i.e., its vibrational frequencies lowered), the mass of the colliding atom is increased, and/or the relative velocity is increased. These effects are consistent with a previously derived impulsive model [J. Chem. Phys. 1970, 52, 5221], which says T → V energy transfer increases as the collisional adiabaticity parameter ξ is decreased.

Original languageEnglish
Pages (from-to)8147-8161
Number of pages15
JournalJournal of physical chemistry
Volume99
Issue number20
DOIs
StatePublished - 1995

Fingerprint Dive into the research topics of 'Energy transfer dynamics in the collision-induced dissociation of Al<sub>6</sub> and Al<sub>13</sub> clusters'. Together they form a unique fingerprint.

Cite this