Emission, Raman spectroscopy, and structural characterization of actinide tetracyanometallates

Branson A Maynard; K Sabrina Lynn; Richard E Sykora; Anne Gorden

doi:10.1021/ic302459z

Emission, Raman spectroscopy, and structural characterization of actinide tetracyanometallates

Branson A Maynard, K Sabrina Lynn, Richard E Sykora, Anne Gorden

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Three new compounds, {U₂(H₂O)₁₀(O)[Pt(CN)₄]₃}·4H₂O, {Th₂(H₂O)₁₀(OH)₂[Pd(CN)₄]₃}·8H₂O, and {(UO₂)₂(DMSO)₄(OH)₂[Ni(CN)₄]}, in the actinide tetracyanometallate, An_x[M(CN)₄]_y, class of compounds have been synthesized and characterized by confocal Raman spectroscopy and single crystal X-ray diffraction. These compounds contain unique structures illustrating dimeric actinide species. The absence of intense charge transfer emission in the visible range for {U₂(H₂O)₁₀(O)[Pt(CN)₄]₃}·4H₂O, as compared to the platinum starting material, is unusual because of the presence of pseudo-one-dimensional Pt···Pt chains in this compound. Confocal Raman spectroscopy of the cyanide stretching region p

Original language	English
Pages (from-to)	4880--4889
Journal	Inorganic Chemistry
DOIs	https://doi.org/10.1021/ic302459z
State	Published - 2013

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title = "Emission, Raman spectroscopy, and structural characterization of actinide tetracyanometallates",

abstract = "Three new compounds, {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, {Th2(H2O)10(OH)2[Pd(CN)4]3}·8H2O, and {(UO2)2(DMSO)4(OH)2[Ni(CN)4]}, in the actinide tetracyanometallate, Anx[M(CN)4]y, class of compounds have been synthesized and characterized by confocal Raman spectroscopy and single crystal X-ray diffraction. These compounds contain unique structures illustrating dimeric actinide species. The absence of intense charge transfer emission in the visible range for {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, as compared to the platinum starting material, is unusual because of the presence of pseudo-one-dimensional Pt···Pt chains in this compound. Confocal Raman spectroscopy of the cyanide stretching region p",

author = "Maynard, {Branson A} and Lynn, {K Sabrina} and Sykora, {Richard E} and Anne Gorden",

year = "2013",

doi = "10.1021/ic302459z",

language = "English",

pages = "4880----4889",

journal = "Inorganic Chemistry",

publisher = "American Chemical Society",

}

TY - JOUR

T1 - Emission, Raman spectroscopy, and structural characterization of actinide tetracyanometallates

AU - Maynard, Branson A

AU - Lynn, K Sabrina

AU - Sykora, Richard E

AU - Gorden, Anne

PY - 2013

Y1 - 2013

N2 - Three new compounds, {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, {Th2(H2O)10(OH)2[Pd(CN)4]3}·8H2O, and {(UO2)2(DMSO)4(OH)2[Ni(CN)4]}, in the actinide tetracyanometallate, Anx[M(CN)4]y, class of compounds have been synthesized and characterized by confocal Raman spectroscopy and single crystal X-ray diffraction. These compounds contain unique structures illustrating dimeric actinide species. The absence of intense charge transfer emission in the visible range for {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, as compared to the platinum starting material, is unusual because of the presence of pseudo-one-dimensional Pt···Pt chains in this compound. Confocal Raman spectroscopy of the cyanide stretching region p

AB - Three new compounds, {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, {Th2(H2O)10(OH)2[Pd(CN)4]3}·8H2O, and {(UO2)2(DMSO)4(OH)2[Ni(CN)4]}, in the actinide tetracyanometallate, Anx[M(CN)4]y, class of compounds have been synthesized and characterized by confocal Raman spectroscopy and single crystal X-ray diffraction. These compounds contain unique structures illustrating dimeric actinide species. The absence of intense charge transfer emission in the visible range for {U2(H2O)10(O)[Pt(CN)4]3}·4H2O, as compared to the platinum starting material, is unusual because of the presence of pseudo-one-dimensional Pt···Pt chains in this compound. Confocal Raman spectroscopy of the cyanide stretching region p

U2 - 10.1021/ic302459z

DO - 10.1021/ic302459z

M3 - Article

SP - 4880

EP - 4889

JO - Inorganic Chemistry

JF - Inorganic Chemistry

ER -

Emission, Raman spectroscopy, and structural characterization of actinide tetracyanometallates

Abstract

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