Abstract
The aim of this research is to create a stronger biopolymer/carbon nanotube composite suited for loadbearing biomedical applications. Electrospinning was used to fabricate a miscible polycaprolactone (PCL)/ polyglycolide (PGA) fiber blend in order to increase the interfacial bonding of the fibers to a PCL matrix. To further increase the strength of the composite, purified single-walled carbon nanotubes (SWNTs) wrapped with double stranded deoxyribonucleic acid (dsDNA) were introduced to the PCL-PGA fibers. Bulk PCL was compression molded to encapsulate the PCL-PGA blended fibers as well as the PCL-PGA/ dsDNA-SWNT fibers. Mechanical properties were determined with three-point bend testing to establish the composite's load transfer capabilities. It was demonstrated that incorporation of PCL-PGA/ dsDNA-SWNT fibers increased the strength and modulus over that of the bulk PCL and PCL-PGA fibers alone. Furthermore, the use of blended fibers allowed load transfer from the dsDNA-SWNTs to the PCL matrix.
Original language | English |
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Pages (from-to) | 476-481 |
Number of pages | 6 |
Journal | Polymer |
Volume | 56 |
DOIs | |
State | Published - Jan 15 2015 |
Keywords
- Carbon nanotubes
- Poly (ε-caprolactone)
- Polyglycolide