TY - JOUR
T1 - Dynamics of the molecular hydrogen ligand in metal complexes
AU - Eckert, Juergen
N1 - Funding Information:
Acknowledgements--wI ould like to expressm y thanks to the many colleaguesw ho have made major contributionst o the work describedh erein,m ostn otablyG . J. KUBAS,t he personw ho first demonstratetdh e existenceo f molecularh ydrogenc omplexesT. hesea lsoi ncludeP . J. HAY, J. H. HALL, C. M. BOYLE, L. VAN DER SLUYS, R. H. MORRIS,H . BLANK, R. P. WHITE, P. VORDERWISCaHn d 0. EISENSTEINM. uch of the experimentawl ork descibedi n this paperw asc arriedo ut at the InstitutL aue-Langevinin Grenoble( France), and I would like to thankm y colleaguesth eref or their collaborationa nd hospitality,p articularlyd uringa one years taya s a visitings cientist.T his work has also benefittedfr om the use of facilitiesa t the Manuel LuganJ r NeutronS catteringC enter,a nationalu serf acilityf undeda s suchb y the Departmenot f Energy,O ffice of Basic Energy Sciences.
PY - 1992/3
Y1 - 1992/3
N2 - The recent discovery that certain metal complexes can bind hydrogen in molecular form as they do other small molecules has presented a unique opportunity for neutron scattering to assist in the determination of electronic details of the novel chemical bond formed between this dihydrogen ligand and the metal. This can be accomplished by comparative studies of the barriers to rotation for the dihydrogen ligand in various complexes where either the metal center or the other metal ligands are changed together with appropriate theoretical analyses. This information can be extracted from vibrational and rotational inelastic neutron scattering spectra. Results from a wide variety of molecular hydrogen complexes are reviewed and their implications for the metal-dihydrogen chemical bond are discussed along with reference to various theortical approaches to this problem.
AB - The recent discovery that certain metal complexes can bind hydrogen in molecular form as they do other small molecules has presented a unique opportunity for neutron scattering to assist in the determination of electronic details of the novel chemical bond formed between this dihydrogen ligand and the metal. This can be accomplished by comparative studies of the barriers to rotation for the dihydrogen ligand in various complexes where either the metal center or the other metal ligands are changed together with appropriate theoretical analyses. This information can be extracted from vibrational and rotational inelastic neutron scattering spectra. Results from a wide variety of molecular hydrogen complexes are reviewed and their implications for the metal-dihydrogen chemical bond are discussed along with reference to various theortical approaches to this problem.
UR - http://www.scopus.com/inward/record.url?scp=0007004383&partnerID=8YFLogxK
U2 - 10.1016/0584-8539(92)80064-4
DO - 10.1016/0584-8539(92)80064-4
M3 - Article
AN - SCOPUS:0007004383
SN - 0584-8539
VL - 48
SP - 363
EP - 378
JO - Spectrochimica Acta Part A: Molecular Spectroscopy
JF - Spectrochimica Acta Part A: Molecular Spectroscopy
IS - 3
ER -