Dye mixtures for ultrafast wavelength shifters

S. Gangopadhyay, N. Barashkov, L. Liu, C. Palsule, W. Borst, R. Wigmans

Research output: Contribution to journalConference articlepeer-review

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Abstract

We have produced fast wavelength shifters using mixtures of various Coumarin dyes with DCM in epoxy-polymers (DGEBA+HHPA) and measured the properties of these wavelength shifters. The particular mixtures were chosen because there is a substantial overlap between the emission spectrum of Coumarin and the absorption spectrum of DCM. The continuous wave and time-resolved fluorescence spectra have been studied as a function of component concentration to optimize the decay times, emission peaks and quantum yields. The mean decay times of these mixtures are in the range of 2.5-4.5 ns. The mean decay time increases with an increase in Coumarin concentration at a fixed DCM concentration or with a decrease in DCM concentration at a fixed Coumarin concentration. This indicates that the energy transfer is radiative at lower relative DCM concentrations and becomes non-radiative at higher DCM concentrations.

Original languageEnglish
Pages (from-to)181-186
Number of pages6
JournalMaterials Research Society Symposium - Proceedings
Volume348
StatePublished - 1994
EventProceedings of the 1994 MRS Spring Meeting - San Francisco, CA, USA
Duration: Apr 4 1994Apr 8 1994

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