Novel ionic liquids (ILs) were designed and synthesized to contain aromatic groups on the imidazolium cation that non-covalently interact with graphene surfaces. This route enables the dispersion of pristine graphene without covalent functionalization or an additive stabilizer; such dispersions are stable against aggregation and display high concentration values. We find that ILs without these aromatic groups are less effective in graphene dispersion, and the dispersed graphene concentration increases with increasing interaction between the cation and graphene surface. Density functional theory (DFT-D3) calculations support the experimental observations and provide a foundation for predictive modeling of IL design for optimal graphene dispersions.
|Number of pages||7|
|Journal||Colloids and Surfaces A: Physicochemical and Engineering Aspects|
|State||Published - Dec 5 2014|
- Ionic liquid
- π-π stacking