Diboron complexes of binucleating bis(amidinate) ligands

Zheng Lu, Nicholas J. Hill, Michael Findlater, Alan H. Cowley

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

The synthesis and X-ray crystal structures of the following bis(amidinate)-substituted boron halides are reported: 1,3-C6H4[C{N(SiMe3)}2BCl2]2 (3), 1,4-C6H4[C{N(SiMe3)}2BCl2]2 (4), 1,4-C6H4[C{N(SiMe3)}2B(Ph)Cl]2 (5), 1,4-C6H4[C{NCy}2BCl2]2 (6), and 1,4-C6H4[C{NCy}2B(Ph)Cl]2 (7). Compounds 3-5 were prepared by trimethylsilyl chloride elimination, while 6 and 7 were prepared via salt metathesis reactions of the appropriate dilithium bis(amidinates) with BCl3 or PhBCl2. The molecular structures of complexes 3, 5, and 6 were determined by single-crystal X-ray diffraction, along with that of the free bis(amidine) 1a.

Original languageEnglish
Pages (from-to)1316-1322
Number of pages7
JournalInorganica Chimica Acta
Volume360
Issue number4
DOIs
StatePublished - Mar 1 2007

Keywords

  • Bis(amidinate)
  • Boron
  • X-ray crystal structure

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