Diastereotopic Group Selectivity In the Deprotonation of (η-Arene)Cr(CO)3 Complexes

Joseph A. Heppert, M. Elizabeth Thomas-Miller, Michael L. Milligan, David Vander Velde, Jeffrey Aubé

Research output: Contribution to journalArticlepeer-review

20 Scopus citations

Abstract

Highly diastereospecific syntheses (de ≥ 94%) of (η-arene)Cr(CO)3 complexes are effected via the group-selective deprotonation of complexes bearing a chiral benzylic directing group. The major diastereomers prepared by this technique are the opposite of those formed in face-selective diastereospecific complexation reactions.

Original languageEnglish
Pages (from-to)2581-2584
Number of pages4
JournalOrganometallics
Volume7
Issue number12
DOIs
StatePublished - Dec 1988

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