Decomposition Kinetics of Chemically Activated Dimethylsilane and Ethylsilane

W. L. Hase; C. J. Mazac; J. W. Simons

doi:10.1021/ja00792a002

Decomposition Kinetics of Chemically Activated Dimethylsilane and Ethylsilane

W. L. Hase, C. J. Mazac, J. W. Simons

Chemistry and Biochemistry

Research output: Contribution to journal › Letter › peer-review

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Abstract

An experimental study of the decomposition kinetics of chemically activated dimethylsilane and ethylsilane produced by reaction of singlet methylene with methylsilane is reported. Rate constants for various possible decomposition paths are deduced and a RRKM theoretical treatment of CH3-Si bond rupture is given. Revised theoretical calculations for previous studies of CH3-Si bond rupture are presented.

Original language	English
Pages (from-to)	3454-3459
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	95
Issue number	11
DOIs	https://doi.org/10.1021/ja00792a002
State	Published - May 1 1973

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title = "Decomposition Kinetics of Chemically Activated Dimethylsilane and Ethylsilane",

abstract = "An experimental study of the decomposition kinetics of chemically activated dimethylsilane and ethylsilane produced by reaction of singlet methylene with methylsilane is reported. Rate constants for various possible decomposition paths are deduced and a RRKM theoretical treatment of CH3-Si bond rupture is given. Revised theoretical calculations for previous studies of CH3-Si bond rupture are presented.",

author = "Hase, {W. L.} and Mazac, {C. J.} and Simons, {J. W.}",

year = "1973",

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T1 - Decomposition Kinetics of Chemically Activated Dimethylsilane and Ethylsilane

AU - Hase, W. L.

AU - Mazac, C. J.

AU - Simons, J. W.

PY - 1973/5/1

Y1 - 1973/5/1

N2 - An experimental study of the decomposition kinetics of chemically activated dimethylsilane and ethylsilane produced by reaction of singlet methylene with methylsilane is reported. Rate constants for various possible decomposition paths are deduced and a RRKM theoretical treatment of CH3-Si bond rupture is given. Revised theoretical calculations for previous studies of CH3-Si bond rupture are presented.

AB - An experimental study of the decomposition kinetics of chemically activated dimethylsilane and ethylsilane produced by reaction of singlet methylene with methylsilane is reported. Rate constants for various possible decomposition paths are deduced and a RRKM theoretical treatment of CH3-Si bond rupture is given. Revised theoretical calculations for previous studies of CH3-Si bond rupture are presented.

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U2 - 10.1021/ja00792a002

DO - 10.1021/ja00792a002

M3 - Letter

AN - SCOPUS:33947087158

SN - 0002-7863

VL - 95

SP - 3454

EP - 3459

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 11

ER -

Decomposition Kinetics of Chemically Activated Dimethylsilane and Ethylsilane

Abstract

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