Debye-waller factors in incoherent inelastic neutron scattering spectra of molecular polycrystals

J. Howard; J. M. Nicol; B. C. Boland; J. Tomkinson; J. Eckert; J. A. Goldstone; A. D. Taylor

doi:10.1080/00268978400102341

Debye-waller factors in incoherent inelastic neutron scattering spectra of molecular polycrystals

J. Howard, J. M. Nicol, B. C. Boland, J. Tomkinson, J. Eckert, J. A. Goldstone, A. D. Taylor

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The incoherent inelastic neutron scattering (I INS) spectrum of HCCo₃(CO)₉ has been obtained in order to test some present methods of calculating band intensities for polycrystalline samples. The fundamental and first overtones of the carbon-hydrogen bending mode were observed at 860 and 1712 cm^-1 respectively. The C-H stretching mode was observed at 3041 cm^-1 and this is the first report of the observation of such a mode in which there is no possibility of confusion with overtone and combination bands.

Original language	English
Pages (from-to)	323-332
Number of pages	10
Journal	Molecular Physics
Volume	53
Issue number	2
DOIs	https://doi.org/10.1080/00268978400102341
State	Published - 1984

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title = "Debye-waller factors in incoherent inelastic neutron scattering spectra of molecular polycrystals",

abstract = "The incoherent inelastic neutron scattering (I INS) spectrum of HCCo3(CO)9 has been obtained in order to test some present methods of calculating band intensities for polycrystalline samples. The fundamental and first overtones of the carbon-hydrogen bending mode were observed at 860 and 1712 cm-1 respectively. The C-H stretching mode was observed at 3041 cm-1 and this is the first report of the observation of such a mode in which there is no possibility of confusion with overtone and combination bands.",

author = "J. Howard and Nicol, {J. M.} and Boland, {B. C.} and J. Tomkinson and J. Eckert and Goldstone, {J. A.} and Taylor, {A. D.}",

note = "Funding Information: We would like to thank SERC for the provision of a research grant. Work at Los Alamos was supported in part by the Division of Basic Energy Sciences, U.S. Department of Energy.",

year = "1984",

doi = "10.1080/00268978400102341",

language = "English",

volume = "53",

pages = "323--332",

journal = "Molecular Physics",

issn = "0026-8976",

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TY - JOUR

T1 - Debye-waller factors in incoherent inelastic neutron scattering spectra of molecular polycrystals

AU - Howard, J.

AU - Nicol, J. M.

AU - Boland, B. C.

AU - Tomkinson, J.

AU - Eckert, J.

AU - Goldstone, J. A.

AU - Taylor, A. D.

N1 - Funding Information: We would like to thank SERC for the provision of a research grant. Work at Los Alamos was supported in part by the Division of Basic Energy Sciences, U.S. Department of Energy.

PY - 1984

Y1 - 1984

N2 - The incoherent inelastic neutron scattering (I INS) spectrum of HCCo3(CO)9 has been obtained in order to test some present methods of calculating band intensities for polycrystalline samples. The fundamental and first overtones of the carbon-hydrogen bending mode were observed at 860 and 1712 cm-1 respectively. The C-H stretching mode was observed at 3041 cm-1 and this is the first report of the observation of such a mode in which there is no possibility of confusion with overtone and combination bands.

AB - The incoherent inelastic neutron scattering (I INS) spectrum of HCCo3(CO)9 has been obtained in order to test some present methods of calculating band intensities for polycrystalline samples. The fundamental and first overtones of the carbon-hydrogen bending mode were observed at 860 and 1712 cm-1 respectively. The C-H stretching mode was observed at 3041 cm-1 and this is the first report of the observation of such a mode in which there is no possibility of confusion with overtone and combination bands.

UR - http://www.scopus.com/inward/record.url?scp=84915167527&partnerID=8YFLogxK

U2 - 10.1080/00268978400102341

DO - 10.1080/00268978400102341

M3 - Article

AN - SCOPUS:84915167527

SN - 0026-8976

VL - 53

SP - 323

EP - 332

JO - Molecular Physics

JF - Molecular Physics

IS - 2

ER -

Debye-waller factors in incoherent inelastic neutron scattering spectra of molecular polycrystals

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