Conformational analysis of 10α-cucurbitadienol

W. David Nes, Rosalind Y. Wong, Mabry Benson, Toshihiro Akihisa

Research output: Contribution to journalArticlepeer-review

21 Scopus citations

Abstract

Evidence has been obtained on the solid state (determined by X-ray crystallography) and solution (determined by 1H and 13C NMR spectroscopy) properties of 10α-cucurbita-5,24-dien-3β-ol which indicate that the molecule orients into a bent rather than flat conformation, the 3β-OH group aligns into the unusual axial rather than the equatorial position, and the side chain orients into the right-handed conformation.

Original languageEnglish
Pages (from-to)1272-1274
Number of pages3
JournalJournal of the Chemical Society, Chemical Communications
Issue number18
DOIs
StatePublished - 1991

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