Cobalt- And iron-catalyzed regiodivergent alkene hydrosilylations

Sheng Zhang, Jia Shia Liao, Daniel K. Unruh, Guigen Li, Michael Findlater

Research output: Contribution to journalArticlepeer-review

Abstract

A complementary set of base metal catalysts has been developed for regiodivergent alkene hydrosilylations: iron complexes of amine-iminopyridine ligands are selective for Markovnikov hydrosilylations (branched/linear up to >99 : 1), while the cobalt complexes bearing the same type of ligands provide excellent levels of anti-Markovnikov selectivity (linear/branched up to >99 : 1). Both systems exhibit high efficiency and wide functional group tolerance.

Original languageEnglish
Pages (from-to)2174-2181
Number of pages8
JournalOrganic Chemistry Frontiers
Volume8
Issue number10
DOIs
StatePublished - May 21 2021

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