Chemo-reductive silylation of hypersilyl arenes - Unusual cleavage of an aromatic C{double bond, long}C double-bond

C. Krempner; H. Reinke; R. Wustrack

doi:10.1016/j.inoche.2006.10.012

Chemo-reductive silylation of hypersilyl arenes - Unusual cleavage of an aromatic C{double bond, long}C double-bond

C. Krempner, H. Reinke, R. Wustrack

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The new compounds 1,1,6,6-tetrakis(trimethylsilyl)-3-tris(trimethylsilyl)silyl-hexa-2,4-diene (3) and 2,4,6-trimethyl-3,4-bis(trimethylsilyl)-1-tris(trimethylsilyl)silyl-cyclohexa-1,5-diene (4b) have been isolated as by-products from the reaction of PhSiCl₃ or MesSiCl₃ with Me₃SiCl and lithium in THF at low temperatures. The X-ray crystal structures of 3 and 4b are reported.

Original language	English
Pages (from-to)	239-242
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	10
Issue number	2
DOIs	https://doi.org/10.1016/j.inoche.2006.10.012
State	Published - Feb 2007

Keywords

Arenes
Dienes
Reductive silylation
Silanes
X-ray crystallography

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title = "Chemo-reductive silylation of hypersilyl arenes - Unusual cleavage of an aromatic C{double bond, long}C double-bond",

abstract = "The new compounds 1,1,6,6-tetrakis(trimethylsilyl)-3-tris(trimethylsilyl)silyl-hexa-2,4-diene (3) and 2,4,6-trimethyl-3,4-bis(trimethylsilyl)-1-tris(trimethylsilyl)silyl-cyclohexa-1,5-diene (4b) have been isolated as by-products from the reaction of PhSiCl3 or MesSiCl3 with Me3SiCl and lithium in THF at low temperatures. The X-ray crystal structures of 3 and 4b are reported.",

keywords = "Arenes, Dienes, Reductive silylation, Silanes, X-ray crystallography",

author = "C. Krempner and H. Reinke and R. Wustrack",

year = "2007",

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doi = "10.1016/j.inoche.2006.10.012",

language = "English",

volume = "10",

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journal = "Inorganic Chemistry Communications",

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T1 - Chemo-reductive silylation of hypersilyl arenes - Unusual cleavage of an aromatic C{double bond, long}C double-bond

AU - Krempner, C.

AU - Reinke, H.

AU - Wustrack, R.

PY - 2007/2

Y1 - 2007/2

N2 - The new compounds 1,1,6,6-tetrakis(trimethylsilyl)-3-tris(trimethylsilyl)silyl-hexa-2,4-diene (3) and 2,4,6-trimethyl-3,4-bis(trimethylsilyl)-1-tris(trimethylsilyl)silyl-cyclohexa-1,5-diene (4b) have been isolated as by-products from the reaction of PhSiCl3 or MesSiCl3 with Me3SiCl and lithium in THF at low temperatures. The X-ray crystal structures of 3 and 4b are reported.

AB - The new compounds 1,1,6,6-tetrakis(trimethylsilyl)-3-tris(trimethylsilyl)silyl-hexa-2,4-diene (3) and 2,4,6-trimethyl-3,4-bis(trimethylsilyl)-1-tris(trimethylsilyl)silyl-cyclohexa-1,5-diene (4b) have been isolated as by-products from the reaction of PhSiCl3 or MesSiCl3 with Me3SiCl and lithium in THF at low temperatures. The X-ray crystal structures of 3 and 4b are reported.

KW - Arenes

KW - Dienes

KW - Reductive silylation

KW - Silanes

KW - X-ray crystallography

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U2 - 10.1016/j.inoche.2006.10.012

DO - 10.1016/j.inoche.2006.10.012

M3 - Article

AN - SCOPUS:33846242172

VL - 10

SP - 239

EP - 242

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

SN - 1387-7003

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