@article{36bb7c3f8800428dae95649f6a040f77,
title = "Catalytic Double [2 + 2] Cycloaddition Relay Enabled C-C Triple Bond Cleavage of Yne-Allenones",
abstract = "An unusual catalytic double [2 + 2] cycloaddition relay reaction of yne-allenones with unactivated alkenes and alkynes has been achieved, which enabled C-C triple-bond cleavage to access more than 60 examples of functionalized phenanthren-9-ols with generally good yields. This reaction provides a regioselective and practical method for the construction of carbocyclic ring systems with a high degree of functional group compatibility. Aside from surveying the scope of this transformation, mechanistic details of this process are provided by conducting systematic theoretical calculations.",
author = "Heng Li and Hao, {Wen Juan} and Mian Wang and Xue Qin and Tu, {Shu Jiang} and Peng Zhou and Guigen Li and Jianyi Wang and Bo Jiang",
note = "Funding Information: We are grateful for financial support from the NSFC (Nos. 21472071 and 21602087), the PAPD of Jiangsu Higher Education Institutions, the Outstanding Youth Fund of JSNU (YQ2015003), the NSF of Jiangsu Province (BK20160212), and the Qing Lan Project of Jiangsu Education Committee. Publisher Copyright: Copyright {\textcopyright} 2018 American Chemical Society.",
year = "2018",
month = jul,
day = "20",
doi = "10.1021/acs.orglett.8b01841",
language = "English",
volume = "20",
pages = "4362--4366",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society (ACS)",
number = "14",
}