During the operation of Magnetic Flux Compression Generators (MFCG), the gas-plasma, shocked by the rapidly expanding armature, could lead to electrical arcing across the gas between the armature and the stator at locations where physical contact between the armature and stator has not yet occurred. This will result in a loss of magnetic flux and a decrease in the electrical efficiency of the MFCG. Therefore, knowledge of the ensuing gas temperature and pressure histories is necessary for identification of loss mechanisms in an effort to optimize the efficiency of MFCGs. This paper describes the procedure for estimating the air temperature and pressure histories via Finite Element (FE) simulation of the armature expansion and its ensuing contact with the stator in an MFCG. First, the validity of the FE model was verified by comparing deformation contours obtained from the simulations to those obtained experimentally via high-speed photography. Utilizing the pressure history data obtained from the FE results, the air temperature was theoretically calculated. The results indicate that the air pressure and temperature in an MFCG, having a compression ratio of 1.8, could be as high as 30 MPa and 4000° Kelvin, respectively.