Attack of isocyanide and carbon monoxide on a bridging alkylidyne ligand at a ditungsten centre. Cleavage of the C-N and C-O triple bonds with respective formation of tungsten-imido and -oxo groups and concomitant addition of the carbon atom to the bridging alkylidyne carbon yielding a bridging σ-W 12-W2 alkynyl ligand

Malcolm H. Chisholm, Joseph A. Heppert, John C. Huffman, William E. Streib

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