Isocyanide ligands and carbon monoxide, C≡X, where X = NBu t, NC6H3Me2-2,6, and O, react in hydrocarbon solvents with [(PriO)2W(μ-CSiMe 3)]2 to give compounds of formula (PriO)(X=) W(μ-CSiMe3)(μ-η2,μ1-CCSiMe 3)W(OPri)3; the compound where X = 2,6-dimethylphenylimido has been characterized by an X-ray study while that for X = O is formulated as an analogue based on i.r. and n.m.r. data.
|Number of pages||3|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1985|