Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes

Zhiliang Yuan; Liangyong Mei; Yin Wei; Min Shi; Padmanabha V. Kattamuri; Patrick McDowell; Guigen Li

doi:10.1039/c2ob07022g

Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes

Zhiliang Yuan, Liangyong Mei, Yin Wei, Min Shi, Padmanabha V. Kattamuri, Patrick McDowell, Guigen Li

Chemistry and Biochemistry

Research output: Contribution to journal › Article

45 Scopus citations

Abstract

Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)-imidazoline-phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.

Original language	English
Pages (from-to)	2509-2513
Number of pages	5
Journal	Organic and Biomolecular Chemistry
Volume	10
Issue number	13
DOIs	https://doi.org/10.1039/c2ob07022g
State	Published - Apr 7 2012

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title = "Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes",

abstract = "Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)-imidazoline-phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.",

author = "Zhiliang Yuan and Liangyong Mei and Yin Wei and Min Shi and Kattamuri, {Padmanabha V.} and Patrick McDowell and Guigen Li",

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doi = "10.1039/c2ob07022g",

language = "English",

volume = "10",

pages = "2509--2513",

journal = "Organic and Biomolecular Chemistry",

issn = "1477-0520",

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Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes. / Yuan, Zhiliang; Mei, Liangyong; Wei, Yin; Shi, Min; Kattamuri, Padmanabha V.; McDowell, Patrick; Li, Guigen.

In: Organic and Biomolecular Chemistry, Vol. 10, No. 13, 07.04.2012, p. 2509-2513.

Research output: Contribution to journal › Article

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T1 - Asymmetric catalytic Mannich-type reaction of hydrazones with difluoroenoxysilanes using imidazoline-anchored phosphine ligand-zinc(II) complexes

AU - Yuan, Zhiliang

AU - Mei, Liangyong

AU - Wei, Yin

AU - Shi, Min

AU - Kattamuri, Padmanabha V.

AU - McDowell, Patrick

AU - Li, Guigen

PY - 2012/4/7

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AB - Asymmetric Mannich-type reaction of hydrazones with difluoroenoxysilanes using chiral zinc(II)-imidazoline-phosphine complexes as catalysts have been established, giving the corresponding adducts in good to excellent enantioselectivity and chemical yields under mild conditions.

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DO - 10.1039/c2ob07022g

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JF - Organic and Biomolecular Chemistry

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