@article{26ae2ebe4d994ccfa56e0d41448bb2ed,
title = "Asymmetric Catalytic Enantio- and Diastereoselective Boron Conjugate Addition Reactions of α-Functionalized α,β-Unsaturated Carbonyl Substrates",
abstract = "An efficient catalytic system has been established for the asymmetric boron conjugate addition of B2pin2 onto α-functionalized (involving C, N, O, and Cl) α,β-unsaturated carbonyls under mild, neutral conditions involving Cu[(S)-(R)-ppfa]Cl, AgNTf2, and alcohols. The dual additives of AgNTf2 and alcohols were found to play crucial roles for achieving high catalytic activity and enantio- and diastereoselectivity (up to 98% ee and 70:1 dr).",
author = "Xie, {Jian Bo} and Siqi Lin and Shuo Qiao and Guigen Li",
note = "Funding Information: We gratefully acknowledge financial support from the NIH (R33DA031860) and the Robert A. Welch Foundation (D-1361). We thank Dr. Daniel Unruh (Texas Tech University) for the X-ray diffraction analysis. We thank Dr. Patrick Commins (New York University Abu Dhabi) for critical reading of the manuscript and helpful comments. Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",
year = "2016",
month = aug,
day = "5",
doi = "10.1021/acs.orglett.6b01998",
language = "English",
volume = "18",
pages = "3926--3929",
journal = "Organic Letters",
issn = "1523-7060",
publisher = "American Chemical Society (ACS)",
number = "15",
}