Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)

Jia Yin Wang; Yao Tang; Guan Zhao Wu; Sai Zhang; Hossein Rouh; Shengzhou Jin; Ting Xu; Yu Wang; Daniel Unruh; Kazimierz Surowiec; Yanzhang Ma; Yunze Li; Courtney Katz; Hongjun Liang; Weilong Cong; Guigen Li

doi:10.1002/chem.202104102

Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)

Jia Yin Wang, Yao Tang, Guan Zhao Wu, Sai Zhang, Hossein Rouh, Shengzhou Jin, Ting Xu, Yu Wang, Daniel Unruh, Kazimierz Surowiec, Yanzhang Ma, Yunze Li, Courtney Katz, Hongjun Liang, Weilong Cong, Guigen Li

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Abstract

Unprecedented chiral multilayer folding 3D polymers have been assembled and regulated by uniform and differentiated aromatic chromophore units between naphthyl piers. Screening catalysts, catalytic systems and monomers were proven to be crucial for asymmetric catalytic Suzuki–Miyaura polycouplings for this assembly. X-ray crystallography of the corresponding dimers and trimers revealed the absolute configuration and the intermolecular packing pattern. Up to 61 960 M_w/41 900 M_n and m/z 4317 for polymers and oligomers, as confirmed by gel permeation chromatography (GPC) and MALDI-TOF MS, indicated that these frameworks were composed of multiple stacked layers. The resulting multiple π-assemblies exhibited remarkable optical properties in aggregated states (photoluminescence in solids and aggregation-induced emission in solutions), as well as reversible redox properties in electrochemical performance.

Original language	English
Article number	e202104102
Journal	Chemistry - A European Journal
Volume	28
Issue number	7
DOIs	https://doi.org/10.1002/chem.202104102
State	Published - Feb 1 2022

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10.1002/chem.202104102

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Wang, J. Y., Tang, Y., Wu, G. Z., Zhang, S., Rouh, H., Jin, S., Xu, T., Wang, Y., Unruh, D., Surowiec, K., Ma, Y., Li, Y., Katz, C., Liang, H., Cong, W., & Li, G. (2022). Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE). Chemistry - A European Journal, 28(7), Article e202104102. https://doi.org/10.1002/chem.202104102

@article{5f2294e5a2c24738b183ce5329bdb0b3,

title = "Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)",

abstract = "Unprecedented chiral multilayer folding 3D polymers have been assembled and regulated by uniform and differentiated aromatic chromophore units between naphthyl piers. Screening catalysts, catalytic systems and monomers were proven to be crucial for asymmetric catalytic Suzuki–Miyaura polycouplings for this assembly. X-ray crystallography of the corresponding dimers and trimers revealed the absolute configuration and the intermolecular packing pattern. Up to 61 960 Mw/41 900 Mn and m/z 4317 for polymers and oligomers, as confirmed by gel permeation chromatography (GPC) and MALDI-TOF MS, indicated that these frameworks were composed of multiple stacked layers. The resulting multiple π-assemblies exhibited remarkable optical properties in aggregated states (photoluminescence in solids and aggregation-induced emission in solutions), as well as reversible redox properties in electrochemical performance.",

author = "Wang, {Jia Yin} and Yao Tang and Wu, {Guan Zhao} and Sai Zhang and Hossein Rouh and Shengzhou Jin and Ting Xu and Yu Wang and Daniel Unruh and Kazimierz Surowiec and Yanzhang Ma and Yunze Li and Courtney Katz and Hongjun Liang and Weilong Cong and Guigen Li",

note = "Funding Information: This work was supported by the Robert A. Welch Foundation (D‐1361‐20210327, USA), and the National Natural Science Foundation of China (22071102 and 91956110). We thank Dr. Yangxue Liu and Liulei Ma for their assistance with syntheses; Prof. K. Hutchins and Q.‐X. Zheng for their assistance with the GPC analysis; Prof. C. Korzeniewski and J. Xu for their assistance with the cyclic voltammetry measurements; Profs. Y. Mechref and S.‐Y. Wang as well as Drs. X. Gong and M. Zabet for their assistance with the MALDI‐TOF analysis and helpful discussions. Publisher Copyright: {\textcopyright} 2021 Wiley-VCH GmbH",

year = "2022",

month = feb,

day = "1",

doi = "10.1002/chem.202104102",

language = "English",

volume = "28",

journal = "Chemistry - A European Journal",

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Wang, JY, Tang, Y, Wu, GZ, Zhang, S, Rouh, H, Jin, S, Xu, T, Wang, Y, Unruh, D, Surowiec, K, Ma, Y, Li, Y, Katz, C, Liang, H, Cong, W & Li, G 2022, 'Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)', Chemistry - A European Journal, vol. 28, no. 7, e202104102. https://doi.org/10.1002/chem.202104102

TY - JOUR

T1 - Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)

AU - Wang, Jia Yin

AU - Tang, Yao

AU - Wu, Guan Zhao

AU - Zhang, Sai

AU - Rouh, Hossein

AU - Jin, Shengzhou

AU - Xu, Ting

AU - Wang, Yu

AU - Unruh, Daniel

AU - Surowiec, Kazimierz

AU - Ma, Yanzhang

AU - Li, Yunze

AU - Katz, Courtney

AU - Liang, Hongjun

AU - Cong, Weilong

AU - Li, Guigen

N1 - Funding Information: This work was supported by the Robert A. Welch Foundation (D‐1361‐20210327, USA), and the National Natural Science Foundation of China (22071102 and 91956110). We thank Dr. Yangxue Liu and Liulei Ma for their assistance with syntheses; Prof. K. Hutchins and Q.‐X. Zheng for their assistance with the GPC analysis; Prof. C. Korzeniewski and J. Xu for their assistance with the cyclic voltammetry measurements; Profs. Y. Mechref and S.‐Y. Wang as well as Drs. X. Gong and M. Zabet for their assistance with the MALDI‐TOF analysis and helpful discussions. Publisher Copyright: © 2021 Wiley-VCH GmbH

PY - 2022/2/1

Y1 - 2022/2/1

N2 - Unprecedented chiral multilayer folding 3D polymers have been assembled and regulated by uniform and differentiated aromatic chromophore units between naphthyl piers. Screening catalysts, catalytic systems and monomers were proven to be crucial for asymmetric catalytic Suzuki–Miyaura polycouplings for this assembly. X-ray crystallography of the corresponding dimers and trimers revealed the absolute configuration and the intermolecular packing pattern. Up to 61 960 Mw/41 900 Mn and m/z 4317 for polymers and oligomers, as confirmed by gel permeation chromatography (GPC) and MALDI-TOF MS, indicated that these frameworks were composed of multiple stacked layers. The resulting multiple π-assemblies exhibited remarkable optical properties in aggregated states (photoluminescence in solids and aggregation-induced emission in solutions), as well as reversible redox properties in electrochemical performance.

AB - Unprecedented chiral multilayer folding 3D polymers have been assembled and regulated by uniform and differentiated aromatic chromophore units between naphthyl piers. Screening catalysts, catalytic systems and monomers were proven to be crucial for asymmetric catalytic Suzuki–Miyaura polycouplings for this assembly. X-ray crystallography of the corresponding dimers and trimers revealed the absolute configuration and the intermolecular packing pattern. Up to 61 960 Mw/41 900 Mn and m/z 4317 for polymers and oligomers, as confirmed by gel permeation chromatography (GPC) and MALDI-TOF MS, indicated that these frameworks were composed of multiple stacked layers. The resulting multiple π-assemblies exhibited remarkable optical properties in aggregated states (photoluminescence in solids and aggregation-induced emission in solutions), as well as reversible redox properties in electrochemical performance.

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U2 - 10.1002/chem.202104102

DO - 10.1002/chem.202104102

M3 - Article

C2 - 34962686

AN - SCOPUS:85122950994

SN - 0947-6539

VL - 28

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 7

M1 - e202104102

ER -

Asymmetric Catalytic Assembly of Triple-Columned and Multilayered Chiral Folding Polymers Showing Aggregation-Induced Emission (AIE)

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