Analysis of electro-kinetics of ammonia oxidation in alkaline media

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Abstract

The kinetics of the electro-oxidation of ammonia in alkaline media on a platinum electrode was studied using a combination of mathematical modeling with rotating disk electrode (KDE) experimental results. It was found that the adsorption of OH is a very important step during the. electro-oxidation of ammonia. The results of the analysis indicate that the mechanisms proposed in the literature for the electro-oxidation of ammonia are in disagreement with the experimental data as they do not consider the adsorption of OH. A new mechanism for the electro-oxidation of ammonia in alkaline media is proposed.

Original languageEnglish
Pages203-213
Number of pages11
StatePublished - 2004
Event206th ECS Meeting - Honolulu, HI, United States
Duration: Oct 3 2004Oct 8 2004

Conference

Conference206th ECS Meeting
CountryUnited States
CityHonolulu, HI
Period10/3/0410/8/04

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