An example of unusual pyridine donor Schiff base uranyl (UO 2 2+) complexes

EE Hardy; KM Wyss; MA Eddy; Anne Gorden

doi:10.1039/C7CC02747H

An example of unusual pyridine donor Schiff base uranyl (UO 2 2+) complexes

EE Hardy, KM Wyss, MA Eddy, Anne Gorden

Chemistry and Biochemistry

Research output: Contribution to journal › Article › peer-review

Abstract

The pentadentate coordination environment of a 2,6-bis[1-[(2-hydroxyphenyl)imino]ethyl] pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium as the uranyl dioxo cation, while fully occupying its equatorial plane. Here, two new uranyl (UO₂²⁺) complexes utilizing this scaffold have been synthesized from successive condensation reactions and subsequent metal complexation. Surprising Zn fluorescence is also discussed.

Original language	English
Pages (from-to)	5718--5720
Journal	Chemical Communications
DOIs	https://doi.org/10.1039/C7CC02747H
State	Published - 2017

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title = "An example of unusual pyridine donor Schiff base uranyl (UO 2 2+) complexes",

abstract = "The pentadentate coordination environment of a 2,6-bis[1-[(2-hydroxyphenyl)imino]ethyl] pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium as the uranyl dioxo cation, while fully occupying its equatorial plane. Here, two new uranyl (UO22+) complexes utilizing this scaffold have been synthesized from successive condensation reactions and subsequent metal complexation. Surprising Zn fluorescence is also discussed.",

author = "EE Hardy and KM Wyss and MA Eddy and Anne Gorden",

year = "2017",

doi = "10.1039/C7CC02747H",

language = "English",

pages = "5718----5720",

journal = "Chemical Communications",

publisher = "Royal Society of Chemistry",

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T1 - An example of unusual pyridine donor Schiff base uranyl (UO 2 2+) complexes

AU - Hardy, EE

AU - Wyss, KM

AU - Eddy, MA

AU - Gorden, Anne

PY - 2017

Y1 - 2017

N2 - The pentadentate coordination environment of a 2,6-bis[1-[(2-hydroxyphenyl)imino]ethyl] pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium as the uranyl dioxo cation, while fully occupying its equatorial plane. Here, two new uranyl (UO22+) complexes utilizing this scaffold have been synthesized from successive condensation reactions and subsequent metal complexation. Surprising Zn fluorescence is also discussed.

AB - The pentadentate coordination environment of a 2,6-bis[1-[(2-hydroxyphenyl)imino]ethyl] pyridine ligand scaffold was designed to accommodate the larger atomic radius of uranium as the uranyl dioxo cation, while fully occupying its equatorial plane. Here, two new uranyl (UO22+) complexes utilizing this scaffold have been synthesized from successive condensation reactions and subsequent metal complexation. Surprising Zn fluorescence is also discussed.

U2 - 10.1039/C7CC02747H

DO - 10.1039/C7CC02747H

M3 - Article

SP - 5718

EP - 5720

JO - Chemical Communications

JF - Chemical Communications

ER -

An example of unusual pyridine donor Schiff base uranyl (UO 2 2+) complexes

Abstract

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