TY - JOUR
T1 - Allyl-Functionalization enhanced thermally stable graphene/fluoroelastomer nanocomposites
AU - Wei, Junhua
AU - Qiu, Jingjing
N1 - Funding Information:
The authors would like to acknowledge the supporting from ACS PRF# 52308-DNI10 grant. The authors also appreciate the help of Mike Kumbalek from Oregon Rubber Mills Co. at Corvallis for the two roll mill mixing process.
PY - 2014/8/5
Y1 - 2014/8/5
N2 - Development of new elastomers with novel functionality has continued since their discovery in order to meet industrial and defense needs in harsh environments. The recent advance of carbon nanomaterials inspired innovative material design strategies and enable more effective production of high-performance elastomers. In this paper, the free radical initiated crosslinking reaction in graphene/fluoroelastomer nanocomposites was studied and the effects of chemical functionalization of graphene nanosheets were analyzed. It indicated that graphene oxide (GO) enhanced fluoroelastomer nanocomposites demonstrated poor high-temperature stability due to the pyrolysis at around 200 °C. In contrast, reduced graphene oxide (RGO) enhanced fluoroelastomer exhibited good thermal stability, but RGO didn't participate in the crosslinking, resulting in very limited improvement in mechanical properties. In this paper, reduced allyl functionalized graphene was studied for the first time to enhance free radical initiated elastomers. The reduced allyl functionalization of graphene was demonstrated to impart superior thermal stability and enhanced mechanical properties to the elastomer matrices. The study of vulcanization kinetics provided insights that the allyl functional groups participated in and accelerated the crosslinking. These results indicated a scalable method to incorporate the advantages of graphene into polymer matrices through free radical reaction. The discovery is very promising to be used in the industry to fabricate gaskets, o-rings, and membranes for high temperature applications.
AB - Development of new elastomers with novel functionality has continued since their discovery in order to meet industrial and defense needs in harsh environments. The recent advance of carbon nanomaterials inspired innovative material design strategies and enable more effective production of high-performance elastomers. In this paper, the free radical initiated crosslinking reaction in graphene/fluoroelastomer nanocomposites was studied and the effects of chemical functionalization of graphene nanosheets were analyzed. It indicated that graphene oxide (GO) enhanced fluoroelastomer nanocomposites demonstrated poor high-temperature stability due to the pyrolysis at around 200 °C. In contrast, reduced graphene oxide (RGO) enhanced fluoroelastomer exhibited good thermal stability, but RGO didn't participate in the crosslinking, resulting in very limited improvement in mechanical properties. In this paper, reduced allyl functionalized graphene was studied for the first time to enhance free radical initiated elastomers. The reduced allyl functionalization of graphene was demonstrated to impart superior thermal stability and enhanced mechanical properties to the elastomer matrices. The study of vulcanization kinetics provided insights that the allyl functional groups participated in and accelerated the crosslinking. These results indicated a scalable method to incorporate the advantages of graphene into polymer matrices through free radical reaction. The discovery is very promising to be used in the industry to fabricate gaskets, o-rings, and membranes for high temperature applications.
KW - Elastomers
KW - Graphene
KW - Vulcanization kinetics
UR - http://www.scopus.com/inward/record.url?scp=84905961436&partnerID=8YFLogxK
U2 - 10.1016/j.polymer.2014.06.063
DO - 10.1016/j.polymer.2014.06.063
M3 - Article
AN - SCOPUS:84905961436
SN - 0032-3861
VL - 55
SP - 3818
EP - 3824
JO - Polymer
JF - Polymer
IS - 16
ER -